674745

(R)-(-)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-Diylhydrogenphosphat

95%

• Synonym(e): (11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1′,2′f]-1,3,2-dioxaphosphepin 4-oxid, MacMillan TiPSY Katalysator
• Empirische Formel (Hill-System): C₅₆H₄₁O₄PSi₂
• CAS-Nummer: 791616-55-2
• Molekulargewicht: 865.07
• NACRES: NA.22
• PubChem Substance ID: 24885235
• UNSPSC Code: 12352005
• MDL number: MFCD09265079

Eigenschaften

• Quality Segment: 100
• assay: 95%
• form: solid
• optical activity: [α]22/D -197°, c = 1 in chloroform
• reaction suitability: reagent type: organic catalyst
• mp: 329-335 °C
• functional group: phosphate
• SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11
• InChI: 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58)
• InChI key: BDQOCXQVIFQJRK-UHFFFAOYSA-N

Beschreibung

Application

Organocatalyst for the first enatioselective organocatalytic reductive amination reaction.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• Gefahrencodes: H315,H319,H335
• Sicherheitshinweise: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): dust mask type N95 (US), Eyeshields, Gloves