668281

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-Hydrotetracarbonyldiruthenium(II)

98%, solid

• Synonym(e): 2,3,4,5-Tetraphenyl-2,4-cyclopentadien-1-on Rutheniumkomplex, Shvo-Katalysator, Tetracarbonyl-μ-hydro[(1,2,3,4,5-h)-1-hydroxylat-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]-diruthenium
• Empirische Formel (Hill-System): C₆₂H₄₂O₆Ru₂
• CAS-Nummer: 104439-77-2
• Molekulargewicht: 1085.13
• MDL number: MFCD03840556
• UNSPSC Code: 12161600
• PubChem Substance ID: 24884974
• NACRES: NA.22

Eigenschaften

• Produktname: 1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-Hydrotetracarbonyldiruthenium(II), 98%
• Quality Segment: 100
• assay: 98%
• form: solid
• reaction suitability: core: ruthenium, reagent type: catalyst
• mp: 223-227 °C
• SMILES string: [Ru][RuH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5.O=C6C(c7ccccc7)=C(c8ccccc8)C(c9ccccc9)=C6c%10ccccc%10
• InChI: 1S/C29H21O.C29H20O.4CO.2Ru.H/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;;;/h1-20,30H;1-20H;;;;;;;
• InChI key: PISMVXYUJBWZFB-UHFFFAOYSA-N

Beschreibung

Application

Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.

Shvo′s Catalyst

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable