If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
Fortfahren mit
577928
Lithium-bis-(trimethylsilyl)-amid -Lösung
1 M in toluene
Synonym(e):
Hexamethyldisilazan Lithiumsalz
Größe auswählen
| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
100 mL | Warenkorb auf Verfügbarkeit prüfen | € 82,60 |
800 mL | Warenkorb auf Verfügbarkeit prüfen | € 366,00 |
Über diesen Artikel
Quality Segment
concentration
1 M in toluene
density
0.860 g/mL at 25 °C
SMILES string
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
General description
Application
- In the deprotonation and nucleophilic difluoromethylation reactions.
- To synthesize isoquinoline derivatives by the addition of N-iodosuccinimide (NIS) to the α-benzyl tosylmethyl isocyanides.
- To prepare arylboronic acid pinacol esters by the reaction of aryl fluorides with bis(pinacolato)diboron via palladium-catalyzed cross-coupling reaction.
1 of 1
Dieser Artikel | |||
|---|---|---|---|
| description 1 M in toluene | description 0.5 M in 2-methyltetrahydrofuran | description 1.0 M in hexanes | description 1.5 M in THF |
| concentration 1 M in toluene | concentration 0.5 M in 2-methyltetrahydrofuran | concentration 1.0 M in hexanes | concentration 1.5 M in THF |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| density 0.860 g/mL at 25 °C | density 0.857 g/mL at 25 °C | density 0.707 g/mL at 25 °C | density 0.893 g/mL at 25 °C |
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Signalwort
Danger
Gefahrencodes
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
Zielorgane
Central nervous system
supp_hazards
Lagerklasse
4.2 - Pyrophoric and self-heating hazardous materials
Was ist los?
WGK 3
Flammpunkt (°F)
48.0 °F - closed cup
Flammpunkt (°C)
8.9 °C - closed cup
PSA (Persönliche Schutzausrüstung)
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Zulassungslistungen
Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.
108-88-3
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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