555142

1-Diphenylphosphin-1′-(di-tert-butylphosphin)ferrocen

solid

• Empirische Formel (Hill-System): C₃₀H₃₆FeP₂
• CAS-Nummer: 95408-38-1
• Molekulargewicht: 514.40
• UNSPSC Code: 12352005
• PubChem Substance ID: 24879174
• NACRES: NA.22
• MDL number: MFCD03701526

Eigenschaften

• Produktname: 1-Diphenylphosphin-1′-(di-tert-butylphosphin)ferrocen,
• form: solid
• Quality Segment: 100
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand; reaction type: Coupling Reactions
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Sustainability features
• mp: 75-79 °C (lit.)
• functional group: phosphine
• SMILES string: [Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4
• InChI: 1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
• InChI key: GQIMIFFIUZZVMJ-UHFFFAOYSA-N

Beschreibung

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is an unsymmetric diphosphine ligand for asymmetric catalysis, combining different phosphine environments to provide enhanced selectivity in metal-catalyzed reactions. Click here for more information.

Application

• Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): Eyeshields, Gloves, type N95 (US)