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418951
(DHQD)2Pyr
97%
Synonym(e):
Hydrochinidin-(2,5-diphenyl-4,6-pyrimidindiyl)-diether
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| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
1 g | Warenkorb auf Verfügbarkeit prüfen | € 194,00 |
Über diesen Artikel
Quality Segment
assay
97%
optical activity
[α]20/D −390°, c = 1.2 in methanol
manufacturer/tradename
ECACC
mp
247-250 °C (lit.)
functional group
phenyl
SMILES string
CC[C@H]1CN2CCC1CC2[C@@H](Oc3nc(nc(O[C@H](C4CC5CCN4C[C@@H]5CC)c6ccnc7ccc(OC)cc67)c3-c8ccccc8)-c9ccccc9)c%10ccnc%11ccc(OC)cc%10%11
InChI
1S/C56H60N6O4/c1-5-35-33-61-27-23-39(35)29-49(61)52(43-21-25-57-47-19-17-41(63-3)31-45(43)47)65-55-51(37-13-9-7-10-14-37)56(60-54(59-55)38-15-11-8-12-16-38)66-53(50-30-40-24-28-62(50)34-36(40)6-2)44-22-26-58-48-20-18-42(64-4)32-46(44)48/h7-22,25-26,31-32,35-36,39-40,49-50,52-53H,5-6,23-24,27-30,33-34H2,1-4H3/t35-,36-,39-,40-,49+,50+,52-,53-/m0/s1
InChI key
SWKRDCRSJPRVNF-DOGDSVMGSA-N
Application
- To catalyze the enantioselective allylic amination of alkylidene cyanoacetates with dialkyl azodicarboxylates.
- To prepare 10(R),11-Dihydroxydihydroquinine and 10(S),11-dihydroxydihydroquinine via the Sharpless catalytic asymmetric dihydroxylation.
- In the total synthesis of okadaic acid, a protein phosphatase inhibitor.
Legal Information
1 of 1
Dieser Artikel | ||
|---|---|---|
| description 97% | description ≥95% | description ≥95% |
| assay 97% | assay ≥95% | assay ≥95% |
| functional group phenyl | functional group - | functional group - |
| Quality Level 100 | Quality Level 200 | Quality Level 200 |
| mp 247-250 °C (lit.) | mp 160 °C (dec.) (lit.) | mp 178 °C (dec.) (lit.) |
| optical activity [α]20/D −390°, c = 1.2 in methanol | optical activity [α]22/D −262°, c = 1.2 in methanol | optical activity [α]22/D +336°, c = 1.2 in methanol |
| manufacturer/tradename ECACC | manufacturer/tradename ECACC | manufacturer/tradename ECACC |
Lagerklasse
11 - Combustible Solids
Was ist los?
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
PSA (Persönliche Schutzausrüstung)
dust mask type N95 (US), Eyeshields, Gloves
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