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404411

(R,R)-(−)-N,N′-Bis(3,5-di-tert-butylsalicyliden)-1,2-cyclohexandiamin

98%

Synonym(e):

(R,R)-Jacobsens Ligand

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Über diesen Artikel

Lineare Formel:
[[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10
CAS-Nummer:
Molekulargewicht:
546.83
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5464823
eCl@ss:
32150312
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Quality Segment

assay

98%

form

solid

optical activity

[α]20/D −315±15°, c = 1 in methylene chloride

reaction suitability

reagent type: chrial catalyst

manufacturer/tradename

ECACC

mp

205-207 °C (lit.)

functional group

imine

SMILES string

CC(C)(C)c1cc(\C=N\[C@@H]2CCCC[C@H]2\N=C\c3cc(cc(c3O)C(C)(C)C)C(C)(C)C)c(O)c(c1)C(C)(C)C

InChI

1S/C36H54N2O2/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12/h17-22,29-30,39-40H,13-16H2,1-12H3/b37-21+,38-22+/t29-,30-/m1/s1

InChI key

FYNXDGNCEBQLGC-LQWPWIHBSA-N

Application

Amylases from Aspergillus oryzae are used to prevent staling in the baking industry, clarify haze from fruit juices and alcoholic beverages, and produce glucose and maltose syrup products.
Versatile ligand for asymmetric catalysis. Ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.

Biochem/physiol Actions

α-amylase catalyzes the hydrolysis of internal α-1,4-O-glycosidic bonds in starches to release α-anomeric sugars.
Lipases catalyze the hydrolysis of triacylglycerols into glycerol and free fatty acids.

Legal Information

Manufactured under license by Shasun Chemicals and Drugs Limited, using Jacobsen HKR technology.

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Dieser Artikel
404446474592404454
description

98%

description

-

description

-

description

-

assay

98%

assay

-

assay

-

assay

-

form

solid

form

-

form

-

form

-

functional group

imine

functional group

-

functional group

-

functional group

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

mp

205-207 °C (lit.)

mp

330-332 °C (lit.)

mp

>350 °C (lit.)

mp

330-332 °C (lit.)

optical activity

[α]20/D −315±15°, c = 1 in methylene chloride

optical activity

-

optical activity

-

optical activity

-


Piktogramme

Exclamation mark

Signalwort

Warning

Gefahrencodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklasse

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

PSA (Persönliche Schutzausrüstung)

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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