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Merck

401781

Sigma-Aldrich

Bis(pentamethylcyclopentadienyl)cobalt(II)

Synonym(e):

CoCp*2, Decamethylcobaltocen

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About This Item

Empirische Formel (Hill-System):
C20H30Co
CAS-Nummer:
Molekulargewicht:
329.39
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.23

Form

solid

Eignung der Reaktion

core: cobalt

mp (Schmelzpunkt)

>210 °C (lit.)

Lagertemp.

2-8°C

SMILES String

[Co].C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

1S/2C10H15.Co/c2*1-6-7(2)9(4)10(5)8(6)3;/h2*1-5H3;

InChIKey

XDHJNPINFJSJJB-UHFFFAOYSA-N

Allgemeine Beschreibung

Bis(pentamethylcyclopentadienyl)cobalt(II) is a powerful electron donor that is widely used as a dopant to prepare molecular semiconductors due to its low solid-state ionization energy (3.3 eV). The dopant improves charge injection and transport in electronic devices.

Anwendung

Bis(pentamethylcyclopentadienyl)cobalt(II) can be used as:
  • An n-type dopant to fabricate organic electronic materials such as copper phthalocyanine thin films.
  • A reducing agent to synthesize high-quality reduced graphene oxide thin films at room temperature.
  • A metal organic precursor for plasma-enhanced atomic layer deposition of cobalt.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type N95 (US)


Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

Plasma-enhanced atomic layer deposition of Co using Co(MeCp)2 precursor
Jusang Park, et al.
Journal of Energy Chemistry, 22, 403-407 (2013)
Decamethylcobaltocene as an efficient n-dopant in organic electronic materials and devices
Calvin K. Chan, et al.
Organic Electronics, 9, 575-581 (2008)
Reduction of Graphene Oxide Thin Films by Cobaltocene and Decamethylcobaltocene
Molly M. MacInnes, et al.
ACS Applied Materials & Interfaces, 10, 2004-2015 (2018)
Carolyn N Valdez et al.
Journal of the American Chemical Society, 140(28), 8924-8933 (2018-06-20)
The effects of a variety of monatomic cations (H+, Li+, Na+, K+, Mg2+, and Ca2+) and larger cations (decamethylcobaltocenium and tetrabutylammonium) on the reduction of colloidal ZnO nanocrystals (NCs) are described. Suspensions of "TOPO"-capped ZnO NCs in toluene/THF were treated

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