394262

Octadecylmagnesiumchlorid -Lösung

0.5 M in THF

• Synonym(e): Chlorooctadecylmagnesium, Octadecane, magnesium complex
• Lineare Formel: CH₃(CH₂)₁₇MgCl
• CAS-Nummer: 116980-66-6
• Molekulargewicht: 313.24
• NACRES: NA.22
• PubChem Substance ID: 24864583
• UNSPSC Code: 12352103
• MDL number: MFCD00012233

Eigenschaften

• Quality Segment: 100
• reaction suitability: reaction type: Grignard Reaction
• packaging: Sure/Seal^™ of
• concentration: 0.5 M in THF
• bp: 67 °C
• density: 0.906 g/mL at 25 °C
• SMILES string: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChI key: ONJPXWZQVLKGIU-UHFFFAOYSA-M

Beschreibung

General description

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

Application

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• supp_hazards: EUH014,EUH019
• Lagerklasse: 3 - Flammable liquids
• Flammpunkt (°F): -4.0 °F - closed cup
• Flammpunkt (°C): -20 °C - closed cup
• PSA (Persönliche Schutzausrüstung): Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
• Gefahrencodes: H225,H302,H314,H335,H336,H351
• Sicherheitshinweise: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Central nervous system, Respiratory system