376345

(1S,3R)-(−)-Camphersäure

99%

• Synonym(e): (−)-Camphersäure, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentandicarbonsäure
• Empirische Formel (Hill-System): C₁₀H₁₆O₄
• CAS-Nummer: 560-09-8
• Molekulargewicht: 200.23
• Beilstein: 1874674
• MDL-Nummer: MFCD00064937
• UNSPSC-Code: 51113400
• PubChem Substanz-ID: 24863434
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 99%
• Optische Aktivität: [α]20/D −48°, c = 10 in ethanol
• mp (Schmelzpunkt): 188-190 °C (lit.)
• SMILES String: CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O
• InChI: 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1
• InChIKey: LSPHULWDVZXLIL-QUBYGPBYSA-N

Beschreibung

Anwendung

(1S,3R)-(−)-Camphoric acid can be used:

• As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
• To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
• To prepare a cobalt(II) coordination polymer named {Co(phen)(H₂O)[C₈H₁₄(COO)₂]}_n·(CH₃OH)_n , wherein “phen” is 1,10-phenanthroline and C₈H₁₄(COOH)₂ is [(1S,3R)-camphoric acid.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)