326348

Eisen(III)-perchlorat Hydrat

crystalline, low chloride

• Synonym(e): Perchloric acid iron(III) salt hydrate
• Lineare Formel: Fe(ClO₄)₃ · xH₂O
• CAS-Nummer: 15201-61-3
• Molekulargewicht: 354.20 (anhydrous basis)
• NACRES: NA.22
• PubChem Substance ID: 24859580
• UNSPSC Code: 12352000
• EC Number: 236-908-0
• MDL number: MFCD00149705
• Form: crystalline

Eigenschaften

• Quality Segment: 200
• form: crystalline
• reaction suitability: reagent type: oxidant
• impurities: <0.005% chloride
• color: pale violet
• SMILES string: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChI key: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Beschreibung

Application

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Sicherheitshinweise

• Piktogramme: GHS03,GHS07
• Signalwort: Danger
• Gefahrencodes: H272,H315,H319,H335
• Sicherheitshinweise: P210 - P220 - P261 - P264 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklasse: 5.1A - Strongly oxidizing hazardous materials
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): Eyeshields, Gloves, type P3 (EN 143) respirator cartridges