297801

2-Amino-3,5-dibrom-benzoesäure-methylester

98%

• Synonym(e): 3,5-Dibrom-anthranilsäure-methylester
• Lineare Formel: Br₂C₆H₂-2-(NH₂)CO₂CH₃
• CAS-Nummer: 606-00-8
• Molekulargewicht: 308.95
• MDL-Nummer: MFCD00010873
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24857930

Eigenschaften

• Assay: 98%
• mp (Schmelzpunkt): 89-91 °C (lit.)
• SMILES String: COC(=O)c1cc(Br)cc(Br)c1N
• InChI: 1S/C8H7Br2NO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3
• InChIKey: NGXVMFCGYYHEGC-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Methyl 2-amino-3,5-dibromobenzoate participates in cobalt(II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones respectively[1]. It also participates in allylic and benzylic oxidation of various cyclic alkenes and benzylic compounds respectively[2].

Anwendung

Methyl 2-amino-3,5-dibromobenzoate was used in the preparation of ethyl 1-(p-methoxyphenyl)-2-oxocyclopentanecarboxylate via reaction with chloroform containing pyridine[3].

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves