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266841
Iridium
wire, diam. 0.15 mm, 99.9% trace metals basis
Synonym(e):
Iridium black
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About This Item
Empirische Formel (Hill-System):
Ir
CAS-Nummer:
Molekulargewicht:
192.22
MDL-Nummer:
UNSPSC-Code:
12352300
PubChem Substanz-ID:
NACRES:
NA.23
Assay
99.9% trace metals basis
Form
wire
Widerstandsfähigkeit
4.71 μΩ-cm
Durchmesser
0.15 mm
bp
4130 °C (lit.)
mp (Schmelzpunkt)
2450 °C (lit.)
Dichte
22.65 g/cm3 (lit.)
SMILES String
[Ir]
InChI
1S/Ir
InChIKey
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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Menge
40mg=10cm, 400mg=100cm
Lagerklassenschlüssel
13 - Non Combustible Solids
WGK
nwg
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Hana Woo et al.
Journal of the American Chemical Society, 135(12), 4771-4787 (2013-03-06)
Despite the promising photofunctionalities, phosphorescent probes have been examined only to a limited extent, and the molecular features that provide convenient handles for controlling the phosphorescence response have yet to be identified. We synthesized a series of phosphorescence zinc sensors
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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