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201170

Phosphor(V)-oxychlorid

ReagentPlus®, 99%

1 of 1 reviewers received a sample product or took part in a promotion

Synonym(e):

Phosphoroxidchlorid, Phosphorylchlorid

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Über diesen Artikel

Lineare Formel:
POCl3
CAS-Nummer:
Molekulargewicht:
153.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
233-046-7
MDL number:
Assay:
99%
Bp:
105.8 °C (lit.)
Vapor pressure:
104 mmHg ( 50 °C), 28 mmHg ( 20 °C)
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Quality Segment

vapor density

5.3 (vs air)

vapor pressure

104 mmHg ( 50 °C), 28 mmHg ( 20 °C)

product line

ReagentPlus®

assay

99%

form

liquid

reaction suitability

reaction type: Halogenations

dilution

(for general lab use)

pH

1 (20 °C)

bp

105.8 °C (lit.)

mp

1.25 °C (lit.)

density

1.645 g/mL at 25 °C (lit.)

functional group

phosphine oxide

SMILES string

ClP(Cl)(Cl)=O

InChI

1S/Cl3OP/c1-5(2,3)4

InChI key

XHXFXVLFKHQFAL-UHFFFAOYSA-N

Application

Phosphor(V)-Oxychlorid (POCl3) ist ein Chlorierungsmittel, das mit Dimethylformamid (DMF) reagiert und ein Vilsmeier-Reagenz für die Vilsmeier-Haack-Formylierungsreaktionen bildet.
Es kann auch als Reagenz bei der Synthese von Folgendes verwendet werden:
  • Chinazolin-4(3H)-on-Derivate aus 2-Aminobenzamiden über die In-situ-Herstellung von Vilsmeier-Reagenz.
  • Substituierte 1-Arylseleno-4-halogen-2-ene durch Behandlung konjugierter Diene mit Arylselenamiden.
  • 3-Methylthioimidazo[1,2-a]pyridine und imidazofusionierte Heterozyklen in Gegenwart von DMSO.

Packaging

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Dieser Artikel
262099214701376949
description

ReagentPlus®, 99%

description

99.999%

description

ReagentPlus®, 99%

description

>95%

Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

assay

99%

assay

99.999%

assay

99%

assay

>95%

form

liquid

form

liquid

form

powder

form

solid

vapor density

5.3 (vs air)

vapor density

5.3 (vs air)

vapor density

4.9 (vs air)

vapor density

-

density

1.645 g/mL at 25 °C (lit.)

density

1.645 g/mL at 25 °C (lit.)

density

2.3 g/mL at 25 °C (lit.)

density

2.82 g/mL at 25 °C (lit.)

pH

1 (20 °C)

pH

1 (20 °C)

pH

1.5 (20 °C, 10 g/L)

pH

-


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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

target_organs

Respiratory Tract

supp_hazards

Lagerklasse

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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