189006

3-(Trifluoracetyl)-D-campher

98%

• Synonym(e): (+)-3-(Trifluoracetyl)campher
• Empirische Formel (Hill-System): C₁₂H₁₅F₃O₂
• CAS-Nummer: 51800-98-7
• Molekulargewicht: 248.24
• Beilstein: 6779716
• EG-Nummer: 257-429-3
• MDL-Nummer: MFCD00003746
• UNSPSC-Code: 12352115
• PubChem Substanz-ID: 24851361
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: liquid
• Optische Aktivität: [α]19/D +148°, c = 2.3 in methylene chloride
• Brechungsindex: n20/D 1.451 (lit.)
• bp: 100-101 °C/16 mmHg (lit.)
• Dichte: 1.172 g/mL at 25 °C (lit.)
• SMILES String: CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)F
• InChI: 1S/C12H15F3O2/c1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1
• InChIKey: ISLOIHOAZDSEAJ-XGLFCGLISA-N

Beschreibung

Anwendung

(+)-3-(Trifluoroacetyl)camphor reacts with suitable chiral ketone precursors to generate chiral dioxiranes in situ, which can catalyse the direct asymmetric epoxidation of unfunctionalized olefins.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 179.6 °F - closed cup
• Flammpunkt (°C): 82 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type ABEK (EN14387) respirator filter