187240

9-Anthracenmethanol

97%

• Synonym(e): 9-Anthrylmethanol
• Empirische Formel (Hill-System): C₁₅H₁₂O
• CAS-Nummer: 1468-95-7
• Molekulargewicht: 208.26
• Beilstein: 1873402
• EG-Nummer: 215-998-5
• MDL-Nummer: MFCD00001264
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24851260
• NACRES: NA.22

Eigenschaften

• Assay: 97%
• Löslichkeit: chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow
• SMILES String: OCc1c2ccccc2cc3ccccc13
• InChI: 1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
• InChIKey: JCJNNHDZTLRSGN-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide.

9-Anthracenemethanol is a derivative of anthracene used in the Diels-Alder reactions.

Anwendung

9-Anthracenemethanol can be used:

• As a starting material to prepare 9-anthracenylmethyl-1-piperazinecarboxylate, which acts as a reagent in the determination of isocyanates using HPLC.
• In the Diels-Alder reaction with dimethylacetylene-dicarboxylate to yield lactone derivatives.
• As an initiator in the ring-opening polymerization of δ-valerolactone to yield poly(δ-valerolactone).
• As a starting material in the synthesis of polymer-supported anthracene, which acts as a dienophile scavenger in cycloaddition reactions.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)