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Key Documents

94907

Sigma-Aldrich

4-Vinylbenzyl chloride

technical, ≥90% (GC), contains 0.1% total stabilizer

Synonym(s):

4-(Chloromethyl)styrene

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About This Item

Linear Formula:
H2C=CHC6H4CH2Cl
CAS Number:
Molecular Weight:
152.62
Beilstein:
2204384
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

grade

technical

Quality Level

Assay

≥90% (GC)

form

liquid

contains

0.05% 4-tert-butylcatechol as stabilizer
0.05% nitroparaffin as stabilizer
0.1% total stabilizer

refractive index

n20/D 1.572 (lit.)
n20/D 1.572

bp

229 °C (lit.)

density

1.083 g/mL at 20 °C
1.083 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClCc1ccc(C=C)cc1

InChI

1S/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2

InChI key

ZRZHXNCATOYMJH-UHFFFAOYSA-N

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Application

  • Influence of functional group concentration on hypercrosslinking of poly (vinylbenzyl chloride) PolyHIPEs: The research investigates how the concentration of 4-vinylbenzyl chloride affects the hypercrosslinking and properties of PolyHIPEs, enhancing their macroporosity (Koler et al., 2021).
  • Optimization of Synthesis of Poly (vinylbenzyl chloride) by RAFT Polymerisation: This study optimizes the RAFT polymerization conditions for synthesizing poly (vinylbenzyl chloride), analyzing the effect of different isomers in the reaction (Allozy & Abd Karim, 2021).
  • Effect of styrene addition on chemically induced grafting of 4-vinylbenzyl chloride onto low-density polyethylene: This paper explores the effects of styrene addition on the graft polymerization of 4-vinylbenzyl chloride onto polyethylene, aiming to improve the material′s properties for use in anion exchange membranes (Chen et al., 2019).
  • Synthesis and characterization of potentially polymerizable amine-derived ionic liquids bearing 4-vinylbenzyl group: The research focuses on synthesizing new amine-derived ionic liquids with 4-vinylbenzyl groups, evaluating their polymerizability and potential applications in materials science (Zajac et al., 2019).

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

219.2 °F - closed cup

Flash Point(C)

104 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Tien D Ho et al.
Analytica chimica acta, 843, 18-26 (2014-08-26)
Super elastic nitinol (NiTi) wires were exploited as highly robust supports for three distinct crosslinked polymeric ionic liquid (PIL)-based coatings in solid-phase microextraction (SPME). The oxidation of NiTi wires in a boiling (30%w/w) H2O2 solution and subsequent derivatization in vinyltrimethoxysilane

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