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376558

Sigma-Aldrich

Yodo

flakes, ReagentPlus®, ≥99%

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About This Item

Fórmula empírica (notación de Hill):
I2
Número de CAS:
7553-56-2
Peso molecular:
253.81
Beilstein:
3587194
Número CE:
231-442-4
Número MDL:
MFCD00011355
Código UNSPSC:
12141916
ID de la sustancia en PubChem:
329755686
NACRES:
NA.21
bp:
184 °C (lit.)
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densidad de vapor

9 (vs air)

Nivel de calidad

100

presión de vapor

0.31 mmHg ( 25 °C)
1 mmHg ( 38.7 °C)

Línea del producto

ReagentPlus®

Ensayo

≥99%

Formulario

flakes

resistividad

1.3E15 μΩ-cm

dilution

(for general lab use)

impurezas

≤0.05% nonvolatile matter

bp

184 °C (lit.)

mp

113 °C (lit.)

cadena SMILES

II

InChI

1S/I2/c1-2

Clave InChI

PNDPGZBMCMUPRI-UHFFFAOYSA-N

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Descripción general

Iodine is a micro nutrient[1] essential for thyroid synthesis.[2] It is a component of Gram′s iodine which has been reported to be used in identifying cellulase-producing microorganisms.[3] Photogeneration of iodine from anatase TiO2 has been studied.[4]

Aplicación

Iodine may be used as a promoter during the synthesis of conjugated molecules with benzofulvene core.[5] It may be employed as a TLC stain for detection of perillyl alcohol.[6]
It may be used as a catalyst in the synthesis of the following:
  • Quinoxalines by reacting 1,2-diamines with 1,2-dicarbonyl compounds under microwave condition.[7]
  • N-Substituted pyrroles via condensation of 2,5-dimethoxy tetrahydrofuran with amines under microwave condition.[8]
  • Disulfidation of alkenes.[9]

Información legal

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

Órganos de actuación

Respiratory system, Thyroid

Código de clase de almacenamiento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCV9638
MKCT9524
MKCT2005
MKCS0009
MKCQ8278

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Farhana Ahad et al.
Indian journal of endocrinology and metabolism, 14(1), 13-17 (2010-01-01)
Iodine is a vital micronutrient required at all stages of life; fetal life and early childhood being the most critical phases of requirement. Diet is the sole source of iodine, which in turn is dependent upon the iodine content of
Debasish Bandyopadhyay et al.
Molecules (Basel, Switzerland), 15(6), 4207-4212 (2010-07-27)
A microwave-induced iodine-catalyzed simple, rapid and convenient synthesis of different types of quinoxalines via condensation of 1,2-diamines with 1,2-dicarbonyl compounds has been accomplished with an excellent yield.
Iodine-catalyzed disulfidation of alkenes.
Wang XR and Chen F.
Tetrahedron, 67(25), 4547-4551 (2011)
Chockalingam Karunakaran et al.
Chemistry Central journal, 5(1), 31-31 (2011-06-18)
The crystal structures of different forms of TiO2 and those of BaTiO3, ZnO, SnO2, WO3, CuO, Fe2O3, Fe3O4, ZrO2 and Al2O3 nanoparticles have been deduced by powder X-ray diffraction. Their optical edges have been obtained by UV-visible diffuse reflectance spectra.
Debasish Bandyopadhyay et al.
Molecules (Basel, Switzerland), 15(4), 2520-2525 (2010-04-30)
An expeditious synthesis of N-substituted pyrroles has been developed by reacting 2,5-dimethoxy tetrahydrofuran and several amines using a microwave-induced molecular iodine-catalyzed reaction under solventless conditions.
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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