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Merck

252360

Sigma-Aldrich

Morpholine

ACS reagent, ≥99.0%

Sinónimos:

Tetrahydro-1,4-oxazine

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5 ML
US$ 129,00
100 ML
US$ 158,00
500 ML
US$ 286,00
1 L
US$ 371,00

US$ 129,00


Fecha estimada de envío28 de mayo de 2025


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5 ML
US$ 129,00
100 ML
US$ 158,00
500 ML
US$ 286,00
1 L
US$ 371,00

About This Item

Fórmula empírica (notación de Hill):
C4H9NO
Número de CAS:
Peso molecular:
87.12
Beilstein:
102549
Número CE:
Número MDL:
Código UNSPSC:
12352100
eCl@ss:
39162409
ID de la sustancia en PubChem:
NACRES:
NA.21

US$ 129,00


Fecha estimada de envío28 de mayo de 2025


Solicitar un pedido a granel

grado

ACS reagent

Nivel de calidad

densidad de vapor

3 (vs air)

presión de vapor

31 mmHg ( 38 °C)
7 mmHg ( 20 °C)

Ensayo

≥99.0%

Formulario

liquid

temp. de autoignición

590 °F

lim. expl.

10.8 %

color

APHA: ≤15

índice de refracción

n20/D 1.454 (lit.)

bp

126.0-130.0 °C
129 °C (lit.)

mp

−7-−5 °C (lit.)

densidad

0.996 g/mL at 25 °C (lit.)

grupo funcional

ether

cadena SMILES

C1COCCN1

InChI

1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2

Clave InChI

YNAVUWVOSKDBBP-UHFFFAOYSA-N

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Aplicación

Morpholine may be used in the preparation of derivatives such as 4-benzoyloxymorpholine[1] and 1-morpholinopropan-1-one.[2] It may also be used in the preparation of (S)-3,3′-bis-morpholinomethyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2-naphthol, a bifunctional chiral catalyst for asymmetric synthesis.[3] As a base, morpholine can be used in the preparation of 1,3-disubstituted allenes from terminal alkynes and aldehydes.[4]

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

87.8 °F - closed cup

Punto de inflamabilidad (°C)

31 °C - closed cup

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Los clientes también vieron

Factors influencing the rate of formation of nitrosomorpholine from morpholine and nitrite: acceleration by thiocyanate and other anions.
T Y Fan et al.
Journal of agricultural and food chemistry, 21(2), 237-240 (1973-03-01)
Synthesis of acylsilanes from morpholine amides. Synthesis of 1-(dimethyl(phenyl)silyl)propan-1-one
Lettan II RB, et al.
Organic Syntheses, 84, 22-22 (2007)
First telomerisation of piperylene with morpholine using palladium-carbene catalysts.
Neubert P, et al.
Catalysis Communications, 77, 70-74 (2016)
Preparation of (S)-3,3'-bis-morpholinomethyl-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol
MTurlington M and Pu L
Organic Syntheses, 87, 59-59 (2010)
Copper-catalyzed electrophilic amination of diorganozinc reagents: 4-phenylmorpholine
Berman AM and Johnson JS
Organic Syntheses, 83, 31-31 (2006)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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