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Merck

747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Sinónimos:

[Ir{dF(CF3)ppy}2(dtbpy)]PF6, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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100 MG
US$ 195,00
1 G
US$ 1.290,00

US$ 195,00


Fecha estimada de envío01 de abril de 2025


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100 MG
US$ 195,00
1 G
US$ 1.290,00

About This Item

Fórmula empírica (notación de Hill):
C42H34F16IrN4P
Número de CAS:
Peso molecular:
1121.91
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22

US$ 195,00


Fecha estimada de envío01 de abril de 2025


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form

solid

Quality Level

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

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Application

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.[1][2][3][4][5]It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.[3]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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Referencia del producto
Descripción
Precios

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Visite la Librería de documentos

Advances in Photocatalysis: A Microreview of Visible Light Mediated Ruthenium and Iridium Catalyzed Organic Transformations.
Teegardin K, et al.
Organic Process Research & Development, 20(7), 1156-1163 (2016)
A photochemical strategy for lignin degradation at room temperature.
Nguyen J D, et al.
Journal of the American Chemical Society, 136(4), 1218-1221 (2014)
Formal Total Synthesis of l-Ossamine via Decarboxylative Functionalization Using Visible-Light-Mediated Photoredox Catalysis in a Flow System.
Inuki S, et al.
The Journal of Organic Chemistry, 82(2), 1248-1253 (2017)
Late?Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis.
DiRocco D A et al.
Angewandte Chemie (International Edition in English), 53(19), 4802-4806 (2014)
Radical Carbon?Carbon Bond Formations Enabled by Visible Light Active Photocatalysts.
Wallentin C J, et al.
Chimia, 66(6), 394-398 (2012)

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Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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