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Merck

698997

Sigma-Aldrich

Poly(3-hexylthiophene-2,5-diyl)

regioregular, average Mn 54,000-75,000, electronic grade, 99.995% trace metals basis

Sinónimos:

Plexcore® OS 2100, P3HT

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About This Item

Fórmula lineal:
(C10H14S)n
Número de CAS:
MDL number:
UNSPSC Code:
12352103

grade

electronic grade

assay

99.995% trace metals basis

form

solid

mol wt

average Mn 54,000-75,000

description

(>98% head-to-tail regioregular (HNMR))

mp

238 °C

orbital energy

HOMO 5 eV 
LUMO 3 eV 

OPV device performance

ITO/NiO/P3HT/PC61BM/LiF/Al

  • Short-circuit current density (Jsc): 11.3 mA/cm2
  • Open-circuit voltage (Voc): 0.64 V
  • Fill Factor (FF): 0.69
  • Power Conversion Efficiency (PCE): 5.16 %

ITO/PEDOT:PSS/P3HT:PC61BM (1:08)/Al
  • Short-circuit current density (Jsc): 9.5 mA/cm2
  • Open-circuit voltage (Voc): 0.63 V
  • Fill Factor (FF): 0.68
  • Power Conversion Efficiency (PCE): 5 %

Mw/Mn

≤2.5

semiconductor properties

P-type (mobility=10−4 - 10−1 cm2/V·s)

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General description

LUMO level 3.1 eV
Poly(3-hexylthiophene) (P3HT) is a regioregular semiconducting polymer. It is used in organic electronics primarily because of its regular end-to-end arrangement of side chain, which allows efficient Π-Π stacking of the conjugated backbones. On account of the alkyl side group, P3HT is rendered hydrophobic in neutral state.

Application

High molecular weight; ultra-high purity P3HT optimized for use in organic photovoltaics (OPV) research and devices. Poly(3-hexylthiophene-2,5-diyl) may be used extensively as a semiconducting layer in organic thin film field effect transistor (FETs) and solar cells.,2

Legal Information

Product of Plextronics, Inc. U.S. Patent 6,166,172.
Plexcore is a registered trademark of Plextronics, Inc.

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Referencia del producto
Descripción
Precios

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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"Control of active semiconducting layer packing in organic thin film transistors through synthetic tailoring of dielectric materials
Singh R, et al.
Royal Society of Chemistry Advances, 4(56), 29383-29392 (2014)
Flexible Transistors Exploiting P3HT on Paper Substrate and Graphene Oxide Film as Gate Dielectric: Proof of Concept.
Valentini L, et al.
Science of Advanced Materials, 5(5), 530-533 (2013)
High sensitivity organic photodiodes with low dark currents and increased lifetimes
Ramuz, M.; Burgi, L.; Winnewisser, C.; et al.
Organic Electronics, 9, 369-376 (2008)
Lei Yang et al.
Physical chemistry chemical physics : PCCP, 14(2), 779-789 (2011-11-26)
Two hole conductor materials, spiro-OMeTAD and P3HT, were compared in solid-state dye-sensitized solar cells. Two organic dyes containing one anchor unit (D35) or two anchor units (M3) were used in the comparison. Absorbed photon to current conversion efficiency close to
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology
Ma, W.; et al.
Advances in Functional Materials, 15, 1617-1622 (2005)

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