529621

Bis(triphenylphosphine)nickel(II) dichloride

99.99% trace metals basis

• Sinónimos: NiCl₂(PPh₃)₂, Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride
• Fórmula lineal: [(C₆H₅)₃P]₂NiCl₂
• Número de CAS: 14264-16-5
• Peso molecular: 654.17
• EC Number: 238-154-8
• MDL number: MFCD00009592
• UNSPSC Code: 12352300
• PubChem Substance ID: 24877695
• NACRES: NA.23

Propiedades

• assay: 99.99% trace metals basis
• form: powder or crystals
• reaction suitability: core: nickel
• mp: 250 °C (dec.) (lit.)
• SMILES string: Cl[Ni]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI key: ZBRJXVVKPBZPAN-UHFFFAOYSA-L

Descripción

Application

Ni(PPh₃)₂Cl₂ may be used to undertake nickel assisted phosphination of biaryl O,N triflates with chlorodiphenylphosphine.

Información de seguridad

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H317,H350,H412
• pcodes: P202 - P261 - P273 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Chronic 3 - Carc. 1B - Skin Sens. 1
• Storage Class: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges