482358

Ferrocenium tetrafluoroborate

technical grade

• Sinónimos: Bis(cyclopentadienyl)iron tetrafluoroborate, Dicyclopentadienyliron fluoborate, Dicyclopentadienyliron tetrafluoroborate
• Fórmula empírica (notación de Hill): C₁₀H₁₀BF₄Fe
• Número de CAS: 1282-37-7
• Peso molecular: 272.84
• MDL number: MFCD00192174
• UNSPSC Code: 12161600
• PubChem Substance ID: 24871823
• NACRES: NA.22

Propiedades

• grade: technical grade
• reaction suitability: core: iron; reagent type: catalyst
• mp: 178 °C (dec.) (lit.)
• SMILES string: [Fe+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
• InChI: 1S/2C5H5.BF4.Fe/c2*1-2-4-5-3-1;2-1(3,4)5;/h2*1-5H;;/q;;-1;+1
• InChI key: ZSPXIHLQPWVOQR-UHFFFAOYSA-N

Descripción

General description

Ferrocenium tetrafluoroborate [FeCp₂][BF₄] is one of the commonly employed ferrocenium salts within chemical synthesis. Ferrocenium salts are commonly used as Lewis acid catalysts, one-electron oxidants, and electron donors.

Application

Ferrocenium tetrafluoroborate serves as:

• an oxidizing agent in the synthesis of the monocationic Co(II)complex [CpCo(azpy)]⁺
• a Lewis acid catalyst in epoxide ring opening and to activatethe carbonyl group for addition or cycloadditions reactions
• an oxidizing agent when used in conjuntion with a Cl^-source
• a reversible redox reagent between stannole dianion and bistannole-1,2-dianion

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges