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Merck

225568

Sigma-Aldrich

Tetrapropylammonium bromide

98%

Sinónimos:

N,N,N-Tripropyl-1-propanaminium bromide

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100 G
US$ 82,10
500 G
US$ 248,00

US$ 82,10

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100 G
US$ 82,10
500 G
US$ 248,00

About This Item

Fórmula lineal:
(CH3CH2CH2)4N(Br)
Número de CAS:
Peso molecular:
266.26
Beilstein:
3567846
Número CE:
Número MDL:
Código UNSPSC:
12352107
ID de la sustancia en PubChem:
NACRES:
NA.22

US$ 82,10

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Nivel de calidad

Ensayo

98%

Formulario

crystals

cadena SMILES

[Br-].CCC[N+](CCC)(CCC)CCC

InChI

1S/C12H28N.BrH/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H/q+1;/p-1

Clave InChI

BGQMOFGZRJUORO-UHFFFAOYSA-M

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Descripción general

Tetrapropylammonium bromide (TPAB) is a quaternary ammonium salt. It is commonly used as a phase-transfer catalyst to facilitate charged species transfer between phases during organic synthesis and various chemical reactions. It also exhibits environmental compatibility, operational simplicity, non-corrosiveness, and ease of reusability, rendering it a suitable material for organic synthesis .[1]

Aplicación

Tetrapropylammonium bromide is used as a structure-directing agent in the synthesis of:
  • ZSM-5 zeolite, which is a major catalyst in the petroleum and fine chemical industries.
  • Microporous and mesoporous materials that have potential applications in electronics (conducting polymers) and catalysis.

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

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A Facile Synthesis of Xanthene-1, 8 (2H)-dione Derivatives by Using Tetrapropylammonium Bromide as Catalyst
Poursattar Marjani A, et al.
Journal of Heterocyclic Chemistry, 55(6), 1324-1330 (2018)
Hui Wang et al.
Physical chemistry chemical physics : PCCP, 17(32), 20636-20646 (2015-07-24)
The (13)C NMR chemical shift moving upfield indicates the main model of π-holeX(-) bond between cyanuric chloride/1,3,5-triazine (3ClN/3N), which possess both the π-hole and σ-hole, and X(-). (13)C NMR and UV absorption titration in acetonitrile confirmed that the bonding abilities
Yong Peng et al.
Angewandte Chemie (International ed. in English), 54(19), 5709-5712 (2015-03-19)
The fabrication of MFI zeolite films with particular b-axis orientation is especially fascinating. Unlike the conventional alkaline or hydrofluoric acid (HF) assisted neutral synthesis route, here we develop a novel neutral synthesis solution system of TPABr/fumed silica/H2 O without the
Sarika Goel et al.
Journal of the American Chemical Society, 136(43), 15280-15290 (2014-10-15)
The encapsulation of metal clusters (Pt, Ru, Rh) within MFI was achieved by exchanging cationic metal precursors into a parent zeolite (BEA, FAU), reducing them with H2 to form metal clusters, and transforming these zeolites into daughter structures of higher
Peng Bai et al.
Nature communications, 6, 5912-5912 (2015-01-22)
Zeolites play numerous important roles in modern petroleum refineries and have the potential to advance the production of fuels and chemical feedstocks from renewable resources. The performance of a zeolite as separation medium and catalyst depends on its framework structure.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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