Saltar al contenido
Merck
Todas las fotos(2)

Documentos clave

Ver Toda la documentación

216607

Sigma-Aldrich

Boron trifluoride diethyl etherate

purified by redistillation, ≥46.5% BF3 basis

Sinónimos:

Boron trifluoride ethyl etherate

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización

Seleccione un Tamaño

100 ML
US$ 105,00
800 ML
US$ 290,00
4 X 25 ML
US$ 322,00

US$ 105,00

PRECIOS SIN IMPUESTOS NACIONALES
Check Cart for Availability
Solicitar un pedido a granel
Todas las fotos(2)

Seleccione un Tamaño

Cambiar Vistas
100 ML
US$ 105,00
800 ML
US$ 290,00
4 X 25 ML
US$ 322,00

About This Item

Fórmula lineal:
BF3 · O(C2H5)2
Número de CAS:
109-63-7
Peso molecular:
141.93
Beilstein:
3909607
Número CE:
203-689-8
Número MDL:
MFCD00013194
Código UNSPSC:
12352106
ID de la sustancia en PubChem:
57647937
NACRES:
NA.22

US$ 105,00

PRECIOS SIN IMPUESTOS NACIONALES
Check Cart for Availability
Solicitar un pedido a granel

densidad de vapor

4.9 (vs air)

presión de vapor

4.2 mmHg ( 20 °C)

Formulario

liquid

purificado por

redistillation

lim. expl.

36 %

concentración

≥46.5% boron trifluoride

índice de refracción

n20/D 1.344 (lit.)

bp

126-129 °C (lit.)

mp

−58 °C (lit.)

densidad

1.15 g/mL (lit.)

grupo funcional

ether

temp. de almacenamiento

2-8°C

cadena SMILES

CC[O+](CC)[B-](F)(F)F

InChI

1S/C4H10BF3O/c1-3-9(4-2)5(6,7)8/h3-4H2,1-2H3

Clave InChI

MZTVMRUDEFSYGQ-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Categorías relacionadas

Aplicación

Catalyst in the synthesis of polyol chains.[1] Reagent for the coupling of imines to allylstannanes[2] and 4′-nitrobenzenesulfenanilide to alkenes and alkynes.[3]

Envase

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Información legal

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 1 Inhalation

Órganos de actuación

Kidney

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

137.3 °F - closed cup

Punto de inflamabilidad (°C)

58.5 °C - closed cup

Equipo de protección personal

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Elija entre una de las versiones más recientes:

Certificados de análisis (COA)

Lot/Batch Number
MKCW0188
MKCS2430
MKCR2398
MKCQ9916
SHBN1593

¿No ve la versión correcta?

Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

Busque por un COA

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Tetrahedron, 50, 12395-12395 (1994)
The Journal of Organic Chemistry, 54, 4739-4739 (1989)
The Journal of Organic Chemistry, 54, 4982-4982 (1989)
U C Reddy et al.
The Journal of organic chemistry, 74(6), 2605-2608 (2009-02-17)
A diastereoselective one-pot, three-component Prins-Friedel-Crafts reaction was developed for the synthesis of 4-aryltetrahydropyran derivatives from the reaction of carbonyl compounds with homoallylic alcohol in the presence of arene promoted by boron trifluoride etherate.
George R Pettit et al.
Journal of natural products, 74(9), 1922-1930 (2011-09-09)
The synthesis of bis-steroidal pyrazines derived from 3-oxo-11,21-dihydroxypregna-4,17(20)-diene (4) and glycosylation of a D-ring side chain with α-L-rhamnose have been summarized. Rearrangement of steroidal pyrazine 10 to 14 was found to occur with boron triflouride etherate. Glycosylation of pyrazine 10
Ver todos los artículos relacionados

Questions

1–4 of 4 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer

    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  4. What is the "acidic gas" referred to in the statement "Water hydrolyzes material liberating acidic gas..." in the MSDS for Product 216607, Boron trifluoride diethyl etherate?

    1 answer

    1. The gas in question is hydrogen fluoride, which is toxic.

      Helpful?

Reviews

No rating value

Active Filters

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico