If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
216143
Fluoruro de tetrabultilamonio solution
1.0 M in THF
Sinónimos:
TBAF solution
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About This Item
Productos recomendados
form
liquid
Quality Level
concentration
1.0 M in THF
impurities
~5 wt. % water
density
0.903 g/mL at 25 °C
functional group
amine
storage temp.
2-8°C
SMILES string
[F-].CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.FH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChI key
FPGGTKZVZWFYPV-UHFFFAOYSA-M
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Application
- Para la desprotección de los grupos sililo y N-sulfonilo.[1][2]
- En las reacciones de fluorinación.[1]
- Para sintetizar indoles 2-sustituidos mediante reacción de ciclación de varias 2-etinilanilinas con alquinos terminales utilizando el catalizador Pd.[3] También puede utilizarse como activador en la síntesis de alquinos arilatados o alquenilados mediante la reacción de acoplamiento de haluros de arilo y alquenilo con alquinos terminales en presencia del catalizador PD.[4]
- Inhibidores de la recaptación triple de monoaminas como nueva generación de antidepresivos
- Alcoholes a través de la hidrólisis de ésteres de alquilsililo a pH neutro en disoluciones tamponadas mixtas orgánico-acuosas
- Oligorribonucleótidos con enlaces fosfonato modificados
- Aril-alquil alcoholes mediante alilación de Nozaki-Hiyama catalizada por ligandos bipiridilodiol quirales y tricloruro de cromo
- Ésteres de ácido dienoico conjugado utilizando reacciones de acoplamiento de Suzuki
- Inhibidor de la Hsp90 o-aminobenzamida macrocíclica con actividad antitumoral
- Inhibidores dobles de fosfoinosítido 3-cinasa (PI3K) y la diana de rapamicina en mamíferos (mTOR)
- Glucósidos poliacetilénicos antidiabetógenos
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Is the Product 216143 suresealed?
1 answer-
The 5 mL quantity is packaged in an amber glass bottle with a screw cap. All other sizes are packaged with the Sure/Seal capping system.
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What causes Product 216143, Tetrabutylammonium fluoride solution, to turn purple?
1 answer-
Our specifications for this product indicate the material should be colorless to yellow in color. Contact with ketones will immediate discoloration sometimes appearing purple in color.
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What applications can 216143 Tetrabutylammonium fluoride solution, be used in?
1 answer-
This product can be used as a fluorinating reagent.
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How should Product 216143, Tetrabutylammonium fluoride solution be stored?
1 answer-
This product is hygroscopic and should be stored under inert gas, such as nitrogen, and at 2-8 deg C, which is in accordance with our MSDS.
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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