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Merck

140910

Sigma-Aldrich

Bathocuproine

greener alternative
Bathocuproine

96%

Sinónimos:

BCP

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500 MG
US$ 103,00
1 G
US$ 166,00

US$ 103,00

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500 MG
US$ 103,00
1 G
US$ 166,00

About This Item

Fórmula empírica (notación de Hill):
C26H20N2
Número de CAS:
Peso molecular:
360.45
Beilstein:
306714
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
NACRES:
NA.23

US$ 103,00

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Ensayo

96%

Formulario

powder

características de los productos alternativos más sostenibles

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

279-283 °C (lit.)

λmáx.

~280 nm in methanol

Energía orbital

HOMO 7 eV 
LUMO 3.5 eV 

rendimiento de la unidad OLED

ITO/CuPc/NPD/TCTA/mCP:FIrpic (6%)/BCP/LiF/Al

  • Color: blue
  • Max. EQE: 4.2 %

ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V

categoría alternativa más sostenible

cadena SMILES

Cc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5

InChI

1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3

Clave InChI

STTGYIUESPWXOW-UHFFFAOYSA-N

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Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Electron transport organic materials have the chemical functionality to transport electrons and are used as electron transport layer in OLED devices. Click here for more information.

Aplicación

Bathocuproine can be used as an electron modificationlayer or interlayer between ETL(electron transport layer) in perovskite solarcells, which can be fabricated using the spin-coating deposition method or thevacuum thermal evaporation method. The addition of bathocuproine enhances thepower conversion efficiency of organic photovoltaic cells.

Pictogramas

Exclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Chronic 4

Código de clase de almacenamiento

11 - Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Certificados de análisis (COA)

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Visite la Librería de documentos

Electromodulation of photoluminescence in vacuum-evaporated films of bathocuproine
Misnik, M., Falkowski, K., Mroz, W., & Stampor, W.
Chemical Physics, 410, 45-54 (2013)
Structural templating as a route to improved photovoltaic performance in copper phthalocyanine/fullerene (C 60) heterojunctions
Sullivan, P., et al.
Applied Physics Letters, 91(23), 233114-233114 (2007)
Development of air stable polymer solar cells using an inverted gold on top anode structure.
Sahin, Yucel, et al.
Thin Solid Films, 476(2), 340-343 (2005)
Kazutaka Hirakawa et al.
Free radical research, 38(5), 439-447 (2004-08-06)
Titanium dioxide (TiO2) is a potential photosensitizer for photodynamic therapy. In this study, the mechanism of DNA damage catalyzed by photo-irradiated TiO2 was examined using [32P]-5'-end-labeled DNA fragments obtained from human genes. Photo-irradiated TiO2 (anatase and rutile) caused DNA cleavage
Douglas Ganini et al.
Free radical biology & medicine, 53(7), 1514-1521 (2012-07-25)
Ceruloplasmin (ferroxidase) is a copper-binding protein known to promote Fe(2+) oxidation in plasma of mammals. In addition to its classical ferroxidase activity, ceruloplasmin is known to catalyze the oxidation of various substrates, such as amines and catechols. Assays based on

Artículos

Explore the eco-friendly potential of organic thin film transistors (OTFTs) for detecting chemical analytes, identifying viruses, and assisting in health diagnostics. This mini-review highlights challenges of achieving sustainability, safety, and biodegradability of each component of an OTFT sensor.

Professor Shinar highlights low-cost, disposable sensor configurations in organic and hybrid electronics for healthcare applications.

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

Questions

1–6 of 6 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the maximum absorbance wavelength for Product 140910, Bathocuproine?

    1 answer
    1. The ?max is at approximately 280 nm in methanol.

      Helpful?

  4. What are the possible applications for Product 140910, Bathocuproine?

    1 answer
    1. It can be used for Cu(I) detection, range 0.1-10 ppm, as it is a Cu(I)-specific colorimetric reagent. It is also an organic electron transporting material.

      Helpful?

  5. What solvents can be used to dissolve Product 140910, Bathocuproine?

    1 answer
    1. This product can be dissolved in 5% pyridine to yield a dark yellow solution. It is also soluble in methanol (36 mg/100ml), isoamyl alcohol (18 mg/100 ml), dioxane (100 mg/ml), 95% ethanol (50 mg/ml) and nitrobenzene.

      Helpful?

  6. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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