398179

Diethanolamine

ACS reagent, ≥98.5%

• Synonym(s): 2,2′-Iminodiethanol, Bis(2-hydroxyethyl)amine
• Linear Formula: HN(CH₂CH₂OH)₂
• CAS Number: 111-42-2
• Molecular Weight: 105.14
• Beilstein: 605315
• EC Number: 203-868-0
• MDL number: MFCD00002843
• UNSPSC Code: 12352100
• PubChem Substance ID: 24864724
• NACRES: NA.21

Properties

• grade: ACS reagent
• Quality Level: 200
• vapor density: 3.6 (vs air)
• vapor pressure: <0.98 atm ( 100 °C)
• Assay: ≥98.5%
• form: solid or liquid
• autoignition temp.: 689 °F
• eq. wt.: 104.0-106.0 Apparent
• expl. lim.: 10.6 %
• impurities: ≤0.15% water; ≤1.0% C₂H₇NO; ≤1.0% C₆H₁₅NO₃
• ign. residue: ≤0.005%
• color: APHA: ≤15
• refractive index: n20/D 1.477 (lit.)
• bp: 217 °C/150 mmHg (lit.)
• mp: 28 °C (lit.)
• solubility: water: soluble 105 g/L at 20 °C
• density: 1.097 g/mL at 25 °C (lit.)
• functional group: amine; hydroxyl
• SMILES string: OCCNCCO
• InChI: 1S/C4H11NO2/c6-3-1-5-2-4-7/h5-7H,1-4H2
• InChI key: ZBCBWPMODOFKDW-UHFFFAOYSA-N

Description

General description

Diethanolamine (DEA) is an amino alcohol commonly used in the preparation of soaps and surfactants, in agricultural chemicals and in textile processing. It is used as an absorbent for capturing CO₂. Its toxic and carcinogenic effect has been studied.

Application

Diethanolamine may be used in the following processes:

• Preparation of disodiumiminodiacetic acid by dehydrogenation.
• As a solvent and reactant in triazine based dendrimer synthesis.
• Preparation of diethanolamine ionic liquids employed in green Heck reaction.

Safety Information

• Pictograms: GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302,H315,H318,H361fd,H373
• Precautionary Statements: P202 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Oral
• Target Organs: Kidney,Liver,Blood
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 2
• Flash Point(F): 280.4 °F - closed cup
• Flash Point(C): 138 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves