927759

Bis(triphenylphosphine)palladium(II) dichloride ChemBeads

• Synonym(s): Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl₂(PPh₃)₂
• Empirical Formula (Hill Notation): C₃₆H₃₀Cl₂P₂Pd
• CAS Number: 13965-03-2
• Molecular Weight: 701.90
• MDL number: MFCD00009593
• UNSPSC Code: 12352302
• NACRES: NA.28

Properties

• form: solid
• Quality Level: 100
• composition: ~ 5 wt.% loading of catalyst
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings
• SMILES string: Cl[Pd]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI key: YNHIGQDRGKUECZ-UHFFFAOYSA-L

Description

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Palladium-catalyzed coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (208671)

Other Notes

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H317,H350i
• Precautionary Statements: P202 - P261 - P272 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Carc. 1B Inhalation - Skin Sens. 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3