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Sigma-Aldrich

Iodine

anhydrous, beads, −10 mesh, 99.999% trace metals basis

Synonym(s):

Diiodine, Molecular iodine

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About This Item

Empirical Formula (Hill Notation):
I2
CAS Number:
7553-56-2
Molecular Weight:
253.81
Beilstein:
3587194
EC Number:
231-442-4
MDL number:
MFCD00011355
UNSPSC Code:
12141916
PubChem Substance ID:
24868599
NACRES:
NA.23

grade

anhydrous

Quality Level

200

vapor density

9 (vs air)

vapor pressure

0.31 mmHg ( 25 °C)
1 mmHg ( 38.7 °C)

Assay

99.999% trace metals basis

form

beads

resistivity

1.3E15 μΩ-cm

particle size

−10 mesh

bp

184 °C (lit.)

mp

113 °C (lit.)

SMILES string

II

InChI

1S/I2/c1-2

InChI key

PNDPGZBMCMUPRI-UHFFFAOYSA-N

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General description

Iodine is an efficient, inexpensive, non-toxic, easy-to-handle electrophilic reagent used in various organic transformations. The electrophilic properties of iodine are effectively utilized in the cyclization of heteroatom-containing alkenyl and alkynyl derivatives. It is also used as an oxidizing agent in the aromatization of α,β-unsaturated cyclohexenone derivatives, and their heterocyclic analogs.

accessory

Product No.
Description
Pricing

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

Target Organs

Respiratory system, Thyroid

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000323516
0000254668
0000211740
0000184689
0000177486

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Iodine puriss., meets analytical specification of Ph. Eur., BP, USP, 99.8-100.5%

Sigma-Aldrich

03002

Iodine

Molecular Iodine-Mediated Cyclization of Tethered Heteroatom-Containing Alkenyl or Alkynyl Systems
Malose Jack Mphahlele
Molecules (Basel), 14 (2009)
Molecular Iodine?An Expedient Reagent for Oxidative Aromatization Reactions of ?,?-Unsaturated Cyclic Compounds
Malose Jack Mphahlele
Molecules (Basel), 14 (2009)
Zulfiqar A Bhutta et al.
Lancet (London, England), 382(9890), 452-477 (2013-06-12)
Maternal undernutrition contributes to 800,000 neonatal deaths annually through small for gestational age births; stunting, wasting, and micronutrient deficiencies are estimated to underlie nearly 3·1 million child deaths annually. Progress has been made with many interventions implemented at scale and
Tim I M Korevaar et al.
The Journal of clinical endocrinology and metabolism, 98(11), 4382-4390 (2013-09-17)
Premature delivery is an important risk factor for child mortality and psychiatric, metabolic, and cardiovascular disease later in life. In the majority of cases, the cause of prematurity cannot be identified. Currently, it remains controversial whether abnormal maternal thyroid function
Elizabeth N Pearce et al.
Thyroid : official journal of the American Thyroid Association, 23(5), 523-528 (2013-03-12)
Dietary iodine intake is required for the production of thyroid hormone. Consequences of iodine deficiency include goiter, intellectual impairments, growth retardation, neonatal hypothyroidism, and increased pregnancy loss and infant mortality. In 1990, the United Nations World Summit for Children established
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