Skip to Content
Merck

242616

Sigma-Aldrich

2-Bromoiodobenzene

99%

Synonym(s):

1-Bromo-2-iodobenzene, 1-Iodo-2-bromobenzene, 2-Bromo-1-iodobenzene, 2-Bromophenyl iodide, 2-Iodo-1-bromobenzene, 2-Iodobromobenzene, o-Bromoiodobenzene, o-Bromophenyl iodide, o-Iodobromobenzene

Sign Into View Organizational & Contract Pricing

Select a Size


Select a Size

Change View

About This Item

Linear Formula:
BrC6H4I
CAS Number:
Molecular Weight:
282.90
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

99%

form

liquid

contains

copper as stabilizer

refractive index

n20/D 1.661 (lit.)

bp

120-121 °C/15 mmHg (lit.)

mp

9-10 °C (lit.)

density

2.203 g/mL at 25 °C (lit.)

functional group

bromo
iodo

SMILES string

Brc1ccccc1I

General description

2-bromoiodobenzene is an electrophile used in Pd-catalyzed cross-coupling reactions with amino-functionalized organozinc reagents. [1] [2]

Application

2-Bromoiodobenzene was used in the synthesis of diarylamines[3].

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Routes toward enantiopure 2-substituted indolines: an overview
Anas, et al.
Tetrahedron Asymmetry, 20, 2193-2199 (2009)
Synthesis of 2-substituted indolines using sequential Pd-catalyzed processes
Deboves, et al.
Journal of the Chemical Society. Perkin Transactions 1, 733-736 (2002)
María E Budén et al.
The Journal of organic chemistry, 74(12), 4490-4498 (2009-05-23)
The synthesis of a series of substituted 9H-carbazoles by the photostimulated S(RN)1 substitution reaction with diarylamines as starting substrate was performed. The diarylamines were obtained by two approaches, the Pd-catalyzed reactions (Buchwald-Hartwig) or Cu-catalyzed reactions of 2-haloanilines with aryl halides
Lei Liu et al.
Journal of pharmaceutical and biomedical analysis, 117, 325-332 (2015-09-29)
The current study reports the development and validation of a stability-indicating reversed phase HPLC method for the separation and identification of potential impurities in vortioxetine, a recently developed antidepressant. The structures of a new compound and four process-related impurities formed

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service