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213241

Sigma-Aldrich

Lithium sulfide

99.98% trace metals basis

Synonym(s):

(lithiosulfanyl)lithium

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About This Item

Empirical Formula (Hill Notation):
Li2S
CAS Number:
Molecular Weight:
45.95
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

grade

battery grade

Quality Level

Assay

99.98% trace metals basis

form

powder

composition

Li2S

reaction suitability

reagent type: catalyst
core: lithium

density

1.66 g/mL at 25 °C (lit.)

application(s)

battery manufacturing
battery manufacturing

storage temp.

2-8°C

SMILES string

[Li]S[Li]

InChI

1S/2Li.S

InChI key

ZWDBUTFCWLVLCQ-UHFFFAOYSA-N

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General description

Lithium sulfide powder is a high-purity, inorganic compound that appears as a white to yellowish crystalline powder. It has a molecular weight of 45.95 g/mol and a density of 1.82 g/cm³. Lithium sulfide is a strong nucleophile and has the chemical formula Li₂S. It readily reacts with water to produce lithium hydroxide and hydrogen sulfide gas. It is also soluble in some organic solvents, such as pyridine and dimethyl sulfoxide.

Application

High-purity lithium sulfide is primarily used as a precursor in the synthesis of other lithium compounds such as lithium thioacetate, lithium tetrafluoroborate, and thio-LISICONs, which are used in lithium-ion batteries among other applications. High-purity lithium sulfide can also be used directly in battery applications as a cathode material in lithium-sulfur batteries. With a theoretical capacity of up to 1166 mAh/g, almost four times that of lithium cobalt oxide, lithium sulfide has gained attention as next-generation cathode material. Additionally, lithium sulfide is used as a precursor in the semiconductor industry for the production of thin-film transistors (TFTs) and other electronic devices, especially lithium sulfide-phosphorus oxide (Li2S-P2O5) TFTs. It is also used in the chemical manufacturing industry as a precursor for lithium hydride, lithium borohydride, and lithium amide, among many other applications.

Features and Benefits

Higher Purity - 99.98%, making it an ideal choice for applications that require higher purity materials.

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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