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419079

Sigma-Aldrich

Chlorobis(2-phenylpyridine)rhodium(III) dimer

98%

Synonym(s):

Di-μ-chlorotetrakis(2-phenylpyridine)dirhodium, Di-μ-chlorotetrakis[2-(2-pyridinyl)phenyl-C,N]dirhodium

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About This Item

Empirical Formula (Hill Notation):
C44H32Cl2N4Rh2
CAS Number:
33915-80-9
Molecular Weight:
893.47
MDL number:
MFCD00191828
UNSPSC Code:
12352300
PubChem Substance ID:
24866090
NACRES:
NA.22

Assay

98%

reaction suitability

core: rhodium
reagent type: catalyst

mp

270 °C (dec.) (lit.)

SMILES string

Cl[Rh](Cl)Cl.Cl[Rh](Cl)Cl.c1ccc(cc1)-c2ccccn2.c3ccc(cc3)-c4ccccn4.c5ccc(cc5)-c6ccccn6.c7ccc(cc7)-c8ccccn8

InChI

1S/4C11H9N.6ClH.2Rh/c4*1-2-6-10(7-3-1)11-8-4-5-9-12-11;;;;;;;;/h4*1-9H;6*1H;;/q;;;;;;;;;;2*+3/p-6

InChI key

QLKGQIHEDKXYJJ-UHFFFAOYSA-H

Application

Reactant for:
  • Chiral octahedral bimetallic assemblies
  • Synthesis of luminescent cyclometalated Rh(II) complexes with carboxylated bipyridyl ligands

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBH6324V
06510PF
13330EB

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