426229
Formic acid-d2
95 wt. % in D2O, 98 atom % D
Synonym(s):
Perdeuterioformic acid
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About This Item
Linear Formula:
DCO2D
CAS Number:
Molecular Weight:
48.04
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.12
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isotopic purity
98 atom % D
Quality Level
Assay
99% (CP)
form
liquid
concentration
95 wt. % in D2O
technique(s)
NMR: suitable
bio NMR: suitable
refractive index
n20/D 1.369 (lit.)
bp
100.8 °C (lit.)
mp
8.2-8.4 °C (lit.)
density
1.273 g/mL at 25 °C
mass shift
M+2
SMILES string
[2H]OC([2H])=O
InChI
1S/CH2O2/c2-1-3/h1H,(H,2,3)/i1D/hD
InChI key
BDAGIHXWWSANSR-PFUFQJKNSA-N
Related Categories
General description
Formic acid-d2 is isotopically labeled formic acid that is used to catalyze isoprene to criegee intermediates. It is used to improve NMR profiling of amino metabolites in biofluids.
Application
Formic acid-d2 is used in the synthesis of N-monodeuteriomethyl-2-substituted piperidines.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
123.8 °F - closed cup
Flash Point(C)
51 °C - closed cup
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G Ottolina et al.
Biochimica et biophysica acta, 998(2), 173-178 (1989-10-05)
The stereospecifically labeled coenzymes [4R-2H]NADH, [4R-2H]NADPH and [4S-2H]NAD(P)H were synthesized enzymatically in high yield and high isotopic purity (greater than or equal to 95%) with 2HCOO2H/formate dehydrogenase, (CH3)2C2HOH/alchol dehydrogenase from Thermoanaerobium brockii and [1-2H]glucose/glucose dehydrogenase, respectively. This set of deuterated
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