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60811

Sigma-Aldrich

Cobalt carbonyl

moistened with hexane (hexane 1-10%), ≥90% (Co)

Synonym(s):

Cobalt tetracarbonyl dimer, Di-μ-carbonylhexacarbonyldicobal, Octacarbonyldicobalt, Dicobalt octacarbonyl

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About This Item

Linear Formula:
Co2(CO)8
CAS Number:
10210-68-1
Molecular Weight:
341.95
MDL number:
MFCD00016024
UNSPSC Code:
12161600
PubChem Substance ID:
57651787
NACRES:
NA.22

Assay

≥90% (Co)

form

solid

quality

moistened with hexane (hexane 1-10%)

reaction suitability

core: cobalt
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Co++].[Co++].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/8CO.2Co/c8*1-2;;/q;;;;;;;;2*+2

InChI key

MQIKJSYMMJWAMP-UHFFFAOYSA-N

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Application

  • Cobalt carbonyl [Co2(CO)8] is commonly used as a catalyst in the hydroformylation (oxo reaction) of alkenes.
  • Along with pyridine, it can be used as a catalyst in the carboxylation of alkenes into corresponding acids and esters.
  • It is employed as a key precursor in the preparation of cobalt platinum (CoPt3), cobalt sulfide (Co3S4) and cobalt selenide (CoSe2) nanocrystals.
  • It is also used as a reagent in Pauson-Khand cyclizations and Nicholas reaction.

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Repr. 2 - Self-heat. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Inhalation

Target Organs

Nervous system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

-9.4 °F

Flash Point(C)

-23 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Octacarbonyldicobalt.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-26 (2014)
A Lewis acid-mediated version of the Nicholas reaction: Synthesis of syn-alkylated products and cobalt-complexed cycloalkynes.
Schreiber SL, et al.
Journal of the American Chemical Society, 108(11), 3128-3130 (1986)
M Varón et al.
Scientific reports, 3, 1234-1234 (2013-02-08)
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Reproducible growth of narrow size distributed ε-Co nanoparticles with a specific size requires full understanding and identification of the role of essential synthesis parameters for the applied synthesis method. For the hot injection methodology, a significant discrepancy with respect to
Gaoxiang Liu et al.
Chemical science, 10(6), 1760-1766 (2019-03-08)
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