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674583

Sigma-Aldrich

Silver perchlorate

anhydrous, 97%

Synonym(s):

Perchloric acid silver(1+) salt, Silver(1+) perchlorate

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About This Item

Linear Formula:
AgClO4
CAS Number:
7783-93-9
Molecular Weight:
207.32
EC Number:
232-035-4
MDL number:
MFCD00003400
UNSPSC Code:
12352302
PubChem Substance ID:
24885223
NACRES:
NA.23

grade

anhydrous

Assay

97%

form

solid

reaction suitability

reagent type: catalyst
core: silver

impurities

≤0.1% Insoluble matter

mp

486 °C (lit.)

solubility

benzene: slightly soluble(lit.)
pyridine: slightly soluble(lit.)

density

2.8 g/mL at 25 °C (lit.)

SMILES string

[Ag+].[O-]Cl(=O)(=O)=O

InChI

1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1

InChI key

YDHABVNRCBNRNZ-UHFFFAOYSA-M

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Application

  • Anion exchange dynamics in the capture of perchlorate by a cationic Ag-based MOF: Investigates the anion exchange dynamics and structural transformations of a silver-based metal-organic framework capturing perchlorate (Colinas et al., 2017).

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H314

Hazard Classifications

Ox. Sol. 2 - Skin Corr. 1B

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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E Petráková et al.
Carbohydrate research, 233, 101-112 (1992-09-02)
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
Glycosylation via Cp2ZrCl2/AgClO4-mediated activation of anomeric sulfoxides.
P Wipf et al.
The Journal of organic chemistry, 66(23), 7910-7914 (2001-11-10)
Ken Sakai et al.
Acta crystallographica. Section B, Structural science, 60(Pt 3), 255-262 (2004-05-19)
The third crystal structure containing the hydroxo-bridged cis-diammineplatinum(II) dimer has been determined for a perchlorate salt of the complex, [Pt(2)(NH(3))(4)(micro-OH)(2)](ClO(4))(2). However, the dinuclear cations in the nitrate and the carbonate salts, [Pt(2)(NH(3))(4)(micro-OH)(2)](NO(3))(2) [Faggiani, Lippert, Lock & Rosenberg (1977). J. Am.
Masafumi Harada et al.
Journal of colloid and interface science, 339(2), 373-381 (2009-09-08)
Metal particles of silver (Ag) were synthesized by the photoreduction of silver perchlorate (AgClO(4)) in water-in-ionic liquid (ILs) microemulsions consisting of Tween 20, water and ionic liquids. The ILs were tetrafluoroborate anions associated with the cations 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF(4)]) and
Raymond Rowan et al.
Medical mycology, 48(3), 498-505 (2010-04-08)
The response of the pathogenic yeast Candida albicans to the silver(I) perchlorate salt (AgClO(4)) was assessed. By employing an anti-phospho-p38 MAPK antibody, dual phosphorylation of a high osmolarity protein (Hog1p) in C. albicans in the presence of AgClO(4) was demonstrated.
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