12902
Potassium hexacyanocobaltate(III)
≥97.0%
Synonym(s):
Tripotassium hexacyanocobaltate(III)
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| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 g | Please contact Customer Service for Availability | HUF 106,000.00 |
About This Item
Linear Formula:
K3Co(CN)6
CAS Number:
Molecular Weight:
332.33
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352202
EC Number:
237-742-1
MDL number:
Assay:
≥97.0%
Form:
crystalline
Quality Level
assay
≥97.0%
form
crystalline
reaction suitability
reagent type: catalyst
core: cobalt
impurities
≤0.1% free cyanide
density
1.878 g/mL at 25 °C (lit.)
anion traces
sulfate (SO42-): ≤500 mg/kg
cation traces
Fe: ≤50 mg/kg
suitability
suitable for acidity or alkalinity (alkalinity <= 0.15 meq/g)
SMILES string
[K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N
Related Categories
Application
Potassiumhexacyanocobaltate(III) can be used as a complexing agent to synthesize double metal cyanide catalyst:
- For the chemoselective reductive amination of carbonyl compounds with aromatic amines to synthesize substituted amines in the presence of polymethylhydrosiloxane as a reducing agent.
- In the ring opening polymerization of propylene oxide to synthesize polyols.
- In the coupling reaction of CO2 with hydrous epoxides to synthesize cyclic carbonates.
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Effect of pH on Retention of 134Cs and 60Co from MAW by Potassium Hexacyanocobaltate(III).
Mekhail FM, et al.
Isotopes in Environmental and Health Studies, 130-133 (1991)
Edward E Little et al.
Environmental science and pollution research international, 14(5), 333-337 (2007-08-29)
Cobalt cyanide complexes often result when ore is treated with cyanide solutions to extract gold and other metals. These have recently been discovered in low but significant concentrations in effluents from gold leach operations. This study was conducted to determine
A 59Co NMR relaxation probe of macromolecule anionic binding sites.
T Raj et al.
Analytical biochemistry, 106(2), 373-376 (1980-08-01)
Shah Raj Ali et al.
Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life, 37(3), 225-234 (2007-03-14)
It has been proposed that metal cyanide complexes would have acted as effective prebiotic catalysts. Insoluble metal cyanide complexes could have concentrated biomonomers from the dilute prebiotic soup, facilitating certain prebiotic reactions. In the light of the above hypothesis, interaction
The reduction of iodopentamminecobalt (III) iodide and potassium hexacyanocobaltate (III) with potassium in liquid ammonia.
Watt GW and Thompson RJ.
J. Inorg. Nucl. Chem., 9(3), 311-314 (1959)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 1225226-30MG | 04065266773934 |
| 65390-1G-F | 04061825848426 |
| M4251-1G | 04061825982489 |
| 75024-25MG | 04061832897929 |
| 65390-250MG-F | 04061832287959 |
| M4251-100MG | 04061834056898 |
| M-171-1ML | 04061833986356 |
| 12902-250G-R | 04061838726056 |
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