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2-Picolylamine

derivatization grade (HPLC), LiChropur, ≥98.0% (GC)

Synonym(s):

2-(Aminomethyl)pyridine

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About This Item

Empirical Formula (Hill Notation):
C6H8N2
CAS Number:
Molecular Weight:
108.14
Beilstein/REAXYS Number:
108054
EC Number:
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:

grade

derivatization grade (HPLC)

Quality Level

assay

≥98.0% (GC)

quality

LiChropur

technique(s)

HPLC: suitable

refractive index

n20/D 1.544 (lit.)
n20/D 1.545-1.547

bp

82-85 °C/12 mmHg (lit.)

density

1.049 g/mL at 25 °C (lit.)

SMILES string

NCc1ccccn1

InChI

1S/C6H8N2/c7-5-6-3-1-2-4-8-6/h1-4H,5,7H2

InChI key

WOXFMYVTSLAQMO-UHFFFAOYSA-N

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General description

2-Picolylamine, a bihaptic nucleophile, is a bidentate ligand that is generally utilized for the preparation of various multidentate ligands and the corresponding complexes.[1][2][3][4][5]

Application

2-Picolylamine may be used as a derivatization agent to enhance the sensitivity of carboxylic acids[6][7] and short-chain fatty acids[8] for their determination in biological samples by liquid chromatography coupled to electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS) and ultra-high performance liquid chromatography (UHPLC), respectively.

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

210.2 °F - closed cup

flash_point_c

99 °C - closed cup


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Copper (II) complexes with sulfonamides derived from 2-picolylamine and their use as chemical nucleases
Macias B, et al.
Inorganica chimica acta, 359(5), 1465-1472 (2006)
Application of 2-Picolylamine Derivatized Ultra-high Performance Liquid Chromatography Tandem Mass Spectrometry for Determination of Short-chain Fatty Acids in Feces Samples
Nagatomo R, et al.
Analytical Sciences, 7(1), 18SCP10-18SCP10 (2018)
Complexes of mono-and bis (2-carboxyethyl)-2-picolylamine: Synthesis and crystal and molecular structures
Pestov AV, et al.
Russian Journal of Coordination Chemistry, 36(10), 769-777 (2010)
Complex-formation reactions and stability constants for mixed-ligand complexes of diaqua (2-picolylamine) palladium (II) with some bio-relevant ligands
El-Sherif AA, et al.
Dalton Transactions, 359(7), 1425-1432 (2003)
Octahedral Bis (2-picolylamine) Complexes of Cobalt (III)
MICHELSEN K
Acta Chemica Scandinavica, 26(2), 7745-7747 (1972)

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