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P62003

Sigma-Aldrich

2-Pyridinecarboxaldehyde

99%

Synonym(s):

Picolinaldehyde, Pyridine-2-aldehyde

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100 G
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About This Item

Empirical Formula (Hill Notation):
C6H5NO
CAS Number:
Molecular Weight:
107.11
Beilstein/REAXYS Number:
105341
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
assay:
99%

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Quality Level

assay

99%

refractive index

n20/D 1.536 (lit.)

bp

181 °C (lit.)

density

1.126 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[H]C(=O)c1ccccn1

InChI

1S/C6H5NO/c8-5-6-3-1-2-4-7-6/h1-5H

InChI key

CSDSSGBPEUDDEE-UHFFFAOYSA-N

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application

2-Pyridinecarboxaldehyde has been used:
  • To synthesize chitosan based bifunctionalized adsorbent.[1]
  • In the aldol addition reaction with pyruvate in the presence of 2-keto-3-deoxy-6-phosphogluconate aldolase (KDPG) catalyst to form (S)-4-hydroxy-2-keto-4-(2′-pyridyl)butyrate.[2]
  • In the condensation reaction with (S)-(−)-α-methylbenzylamine and (R)-(+)-α-methylbenzylamine to synthesize two chiral (S)-(−)- and (R)-(+)Schiff base compounds.[3]

It can also be combined with thiosemicarbazide to form 2-pyridinecarboxaldehyde thiosemicarbazone ligand (L) which can further complex with Ni(II) and Cu(II) salts (MX) to form [M(L)2X2] complexes.[4]

pictograms

Skull and crossbonesCorrosion

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 2

flash_point_f

170.6 °F

flash_point_c

77 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Bifunctionalized chitosan: A versatile adsorbent for removal of Cu (II) and Cr (VI) from aqueous solution
Moreira ALSL, et al.
Carbohydrate Polymers, 201, 218-227 (2018)
Bacterial biodegradability of inhibitors of chiral imine type corrosion and catabolic prediction
Bautista Garcia JE, et al.
REVISTA INTERNACIONAL DE CONTAMINACION AMBIENTAL, 31(4), 415-426 (2015)
Olga Yu Vassilyeva et al.
Dalton transactions (Cambridge, England : 2003), 48(30), 11278-11284 (2019-07-04)
The novel organic-inorganic hybrid salt [L]2[CoCl4] (1) and molecular complex [CoLCl3] (2), where L+ is 2-methyl-3-(pyridin-2-yl)imidazo[1,5-a]pyridinium cation, feature simple {CoCl4} and {CoCl3N} tetrahedral environments of negligible (1) and a slightly higher distortion (2) that are responsible for rather low positive
Gaganpreet Kaur et al.
Dalton transactions (Cambridge, England : 2003), 47(16), 5595-5606 (2018-03-17)
The unregulated use of organophosphates (OPs) as pesticides and toxic chemical warfare agents demands their continuous monitoring from a human health perspective. This study describes a fluorescence turn-on sensing assay for the selective quantification of OPs in aqueous medium. Metal
Ferenc Matyuska et al.
Dalton transactions (Cambridge, England : 2003), 46(26), 8626-8642 (2017-06-27)
Manganese(ii), copper(ii) and zinc(ii) complexes of four polydentate tripodal ligands (tachpyr (N,N',N''-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane), trenpyr (tris[2-(2-pyridylmethyl)aminoethyl]amine, tach3pyr (N,N',N''-tris(3-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane) and tren3pyr (tris[2-(2-pyridylmethyl)aminoethyl]amine)) were characterized in both solution and solid states. A combined evaluation of potentiometric, UV-VIS, NMR and EPR data allowed the conclusion

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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