151939

Methanol-OD

99.5 atom % D

• Synonym(s): mono-Deuteromethanol, Methan(ol-d), Methyl alcohol-OD
• Linear Formula: CH₃OD
• CAS Number: 1455-13-6
• Molecular Weight: 33.05
• Beilstein/REAXYS Number: 1730948
• EC Number: 215-933-0
• MDL number: MFCD00044213
• UNSPSC Code: 12142201
• PubChem Substance ID: 24849182
• NACRES: NA.21

Properties

• isotopic purity: 99.5 atom % D
• Quality Level: 100
• assay: 99% (CP)
• form: liquid
• expl. lim.: 5.5-36.5 % (lit.)
• technique(s): NMR: suitable
• impurities: ≤0.0250% water; water
• refractive index: n20/D 1.327 (lit.)
• bp: 65.5 °C (lit.)
• mp: -99 °C (lit.)
• density: 0.813 g/mL at 25 °C (lit.)
• mass shift: M+1
• SMILES string: [2H]OC
• InChI: 1S/CH4O/c1-2/h2H,1H3/i2D
• InChI key: OKKJLVBELUTLKV-VMNATFBRSA-N

Description

General description

Methan(ol-d) (Methanol-OD, CH₃OD) is a deuterated form of methanol. Dissociation of CH₃OD adsorbed on the clean W(100) surface resulted in the formation of hydrogen, carbon and oxygen (β-CO). Additionally, carbon dioxide, water and methyl formate were obtained when similar dissociation was conducted over the W(100)-(5×1)C surface. The dissociation process was monitored by temperature-programmed reaction spectroscopy. Self-diffusion coefficient, shear viscosities and densities of liquid CH₃OD have been determined by NMR spin-echo technique.

Application

Methanol-OD may have been used as solvent during cis-to-trans thermal isomerization of 1,3-diphenyltriazene using laser-induced optoacoustic calorimetry technique.

Recommended products

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

Safety Information

• pictograms: GHS02,GHS06,GHS08
• signalword: Danger
• hcodes: H225,H301 + H311 + H331,H370
• pcodes: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 2
• flash_point_f: 51.8 °F - closed cup
• flash_point_c: 11.0 °C - closed cup