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Sigma-Aldrich

Sodium borodeuteride

98 atom % D, 90% (CP)

Synonym(s):

Deuterated sodium borohydride, Sodium tetradeuterioboron

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About This Item

Linear Formula:
NaBD4
CAS Number:
15681-89-7
Molecular Weight:
41.86
EC Number:
239-764-7
MDL number:
MFCD00003519
UNSPSC Code:
12352103
PubChem Substance ID:
24852210
NACRES:
NA.12

isotopic purity

98 atom % D

assay

90% (CP)

autoignition temp.

752 °F

mp

>300 °C (dec.) (lit.)

density

1.187 g/mL

mass shift

M+4

SMILES string

[Na+].[2H][B-]([2H])([2H])[2H]

InChI

1S/BH4.Na/h1H4;/q-1;+1/i1D4;

InChI key

YOQDYZUWIQVZSF-XWFVQAFUSA-N

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General description

Sodium borodeuteride is an inorganic compound with chemical formula NaBD4. The sodium borodeuteride is a stable isotope and is commonly used as a reducing agent.

Application

Sodium borodeuteride is used:
  • As a reducing agent in the asymmetric reduction of carbonyl groups in presence Sn-mediated catalyst.
  • In the deuteration of quinoxalinones with olefins in presence of Iron(III) promoted catalyst.
  • In the synthesis of amine borane and amine trideuterioborane adducts in presence of NaBH4(sodium borohydride) and crown-ether-catalyst.

Features and Benefits

Sodium borodeuteride is
  • An easily handled reducing agent.
  • Commercially available deuteride source.

Packaging

This product may be available from bulk stock and can be packaged on demand. For information on pricing, availability and packaging, please contact Stable Isotopes Customer Service.

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react 1

supp_hazards

EUH014

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tetrahedron Letters, 48, 2335-2335 (2007)
Journal of Organometallic Chemistry, 469, 15-15 (1994)
Synthesis, 4013-4013 (2006)
Xiao-Dan Shi et al.
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Dictyophora echinovolvata is a kind of edible mushroom in the Dictyophora genus, of which polysaccharide is an important chemical substance. Herein, three polysaccharide fractions (DEP-4P, DEP-6P and DEP-8P) were prepared from water extract of D. echinovolvata using gradient ethanol precipitation
Khalef Lefsih et al.
Phytochemistry, 154, 47-55 (2018-07-15)
This work aims to fill the gap in the present knowledge about the structure of pectin from Opuntia ficus-indica. The water-soluble pectin (WSP) fraction, extracted with the Microwave Assisted Extraction (MAE), was further deproteinated (dWSP) and analyzed through several biophysical
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