908711
Ni(IMes)(di-t-butyl fumarate)2
Synonym(s):
Montgomery Ni catalyst
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About This Item
Empirical Formula (Hill Notation):
C45H64N2NiO8
CAS Number:
Molecular Weight:
819.69
UNSPSC Code:
12352103
NACRES:
NA.22
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form
powder
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
Application
Ni(IMes)(di-t-butyl fumarate)2 is an NHC-Ni(0) precatalyst developed in the Montgomery lab used for a variety of synthetic transformations including reductive couplings of aldehydes and alkynes and N-arylation of amines.
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Product No.
Description
Pricing
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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Alex J Nett et al.
ACS catalysis, 8(7), 6606-6611 (2018-08-07)
The synthesis and catalytic activity of several classes of NHC-Ni(0) pre-catalysts stabilized by electron-withdrawing alkenes are described. Variations in the structure of fumarate and acrylate ligands modulate the reactivity and stability of the NHC-Ni(0) pre-catalysts and lead to practical and
Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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