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766119

Sigma-Aldrich

5-Fluoro-2-pyridylzinc bromide solution

0.6 M in THF

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About This Item

Empirical Formula (Hill Notation):
C5H3BrFNZn
CAS Number:
935433-87-7
Molecular Weight:
241.38
MDL number:
MFCD13152556
UNSPSC Code:
12352103
PubChem Substance ID:
329767209
NACRES:
NA.22

form

solution

reaction suitability

core: zinc
reagent type: catalyst
reaction type: Negishi Coupling

concentration

0.6 M in THF

impurities

<5% free chloride

density

1.002 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Fc1ccc([Zn]Br)nc1

InChI

1S/C5H3FN.BrH.Zn/c6-5-2-1-3-7-4-5;;/h1-2,4H;1H;/q;;+1/p-1

InChI key

GUNYTXBFDVSHAJ-UHFFFAOYSA-M

Application

Nucleophlic reagent applicable for substitution and addition reactions. Also could be used in cross coupling reactions (Negishi couplings).


technical-documents

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-2.2 °F

flash_point_c

-19 °C

Certificates of Analysis (COA)

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