279811

Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate

98%

• Synonym(s): Cobaltocenium hexafluorophosphate
• Empirical Formula (Hill Notation): C₁₀H₁₀CoF₆P
• CAS Number: 12427-42-8
• Molecular Weight: 334.08
• EC Number: 235-655-3
• MDL number: MFCD00011874
• UNSPSC Code: 12161600
• PubChem Substance ID: 24856910
• NACRES: NA.22

Properties

• assay: 98%
• reaction suitability: core: cobalt; reagent type: catalyst
• SMILES string: [Co+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F
• InChI: 1S/2C5H5.Co.F6P/c2*1-2-4-5-3-1;;1-7(2,3,4,5)6/h2*1-5H;;/q;;+1;-1
• InChI key: IASMSXQWVNBFOM-UHFFFAOYSA-N

Description

Application

Uses:

• Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
• Reactant for modification of organometallic electrodes surfaces through cathodic reduction
• Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302 + H312 + H332,H315,H319,H335
• pcodes: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves