Skip to Content
MilliporeSigma
All Photos(2)

Documents

731110

Sigma-Aldrich

Di-n-butylmagnesium solution

greener alternative

1 M in ether and hexanes

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
[CH3(CH2)3]2Mg
CAS Number:
1191-47-5
Molecular Weight:
138.53
Beilstein/REAXYS Number:
3535184
MDL number:
MFCD00015225
UNSPSC Code:
26111700
PubChem Substance ID:
329764622
NACRES:
NA.23

form

solution

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

1 M in ether and hexanes

density

0.736 g/mL at 25 °C

greener alternative category

Enabling,

SMILES string

CCCC[Mg]CCCC

InChI

1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;

InChI key

ODHFJIDDBSDWNU-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Di-n-butylmagnesium solution may be prepared by hydrogenation of magnesium, followed by reacting it with 1-butene.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Electrochemically inactive [Mg2(μ-Cl)3•6THF][C2H5AlCl3] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS2 or WO2Cl2. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

supp_hazards

EUH014,EUH019

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk_germany

WGK 3

flash_point_f

-22.0 °F

flash_point_c

-30 °C

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

King RB
Organometallic Syntheses null
Multivalent cation intercalation
Bruce PG, et al.
Solid State Ionics, 53-56(1), 351-355 (1992)
Some novelties in olefin carbometallation assisted by alkyl-magnesium and-aluminium derivatives and catalyzed by zirconium and titanium complexes.
Dzhemilev UM and Vostrikova OS
Journal of Organometallic Chemistry, 285(1), 43-51 (1985)
Hee Soo Kim et al.
Nature communications, 2, 427-427 (2011-08-11)
Magnesium metal is an ideal rechargeable battery anode material because of its high volumetric energy density, high negative reduction potential and natural abundance. Coupling Mg with high capacity, low-cost cathode materials such as electrophilic sulphur is only possible with a
Chemical and physical evidence for metal?metal interchange between lithium alkoxides and di-n-butylmagnesium.
Micha Screttas M, et al.
Tetrahedron Letters, 43(27), 4871-4873 (2002)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service