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71208

Sigma-Aldrich

Sodium ethanethiolate

technical, ~90% (RT)

Synonym(s):

Ethanethiol sodium salt, Ethyl mercaptan sodium salt

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$186.00
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10 G
$186.00
50 G
$594.15

About This Item

Linear Formula:
CH3CH2SNa
CAS Number:
811-51-8
Molecular Weight:
84.12
Beilstein/REAXYS Number:
3593647
MDL number:
MFCD00066318
UNSPSC Code:
12352100
PubChem Substance ID:
57652230
NACRES:
NA.22

$186.00

Available to ship onApril 29, 2025Details

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grade

technical

Quality Level

200

assay

~90% (RT)

form

crystals

SMILES string

CCS[Na]

InChI

1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1

InChI key

QJDUDPQVDAASMV-UHFFFAOYSA-M

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Application

Sodium ethanethiolate is a reagent generally used to synthesize various thioethers.[1][2] It can be employed as a ligand in the preparation of organometallic complexes.[3][4] It is also used in the synthesis of thiolated amino-alcohols.[5]

Other Notes

Alkanethiolates are efficient reagents for SN2 dealkylation of esters and aryl ethers[6][7][8][9][10]

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH029

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM9554
BCCJ0461
BCCG0146
BCCF1420
BCCD0583

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G.I. Feutrill et al.
Tetrahedron Letters, 1327-1327 (1970)
Novel thiolated amino-alcohols as chiral ligands for copper-catalyzed asymmetric nitro-aldol reactions.
Mansawat, Woraluk et al.
Tetrahedron Letters, 48(24), 4235-4238 (2007)
P.A. Bartlett et al.
Tetrahedron Letters, 4459-4459 (1970)
Mononuclear Ni (III) Complexes [NiIII (L)(P (C6H3-3-SiMe3-2-S) 3)] 0/1-(L= Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases.
Lee, Chien-Ming et al.
Inorganic Chemistry, 45(26), 10895-10904 (2006)
K. Lal et al.
The Journal of Organic Chemistry, 52, 1072-1072 (1987)
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