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71208

Sigma-Aldrich

Sodium ethanethiolate

technical, ~90% (RT)

Synonym(s):

Ethanethiol sodium salt, Ethyl mercaptan sodium salt

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About This Item

Linear Formula:
CH3CH2SNa
CAS Number:
811-51-8
Molecular Weight:
84.12
Beilstein/REAXYS Number:
3593647
MDL number:
MFCD00066318
UNSPSC Code:
12352100
PubChem Substance ID:
57652230
NACRES:
NA.22

grade

technical

Quality Level

200

assay

~90% (RT)

form

crystals

SMILES string

CCS[Na]

InChI

1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1

InChI key

QJDUDPQVDAASMV-UHFFFAOYSA-M

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application

Sodium ethanethiolate is a reagent generally used to synthesize various thioethers. It can be employed as a ligand in the preparation of organometallic complexes. It is also used in the synthesis of thiolated amino-alcohols.

Other Notes

Alkanethiolates are efficient reagents for SN2 dealkylation of esters and aryl ethers

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH029

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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G.I. Feutrill et al.
Tetrahedron Letters, 1327-1327 (1970)
Novel thiolated amino-alcohols as chiral ligands for copper-catalyzed asymmetric nitro-aldol reactions.
Mansawat, Woraluk et al.
Tetrahedron Letters, 48(24), 4235-4238 (2007)
P.A. Bartlett et al.
Tetrahedron Letters, 4459-4459 (1970)
Kojyl thioether derivatives having both tyrosinase inhibitory and anti-inflammatory properties.
Rho, Ho Sik et al.
Bioorganic & Medicinal Chemistry Letters, 20(22), 6569-6571 (2010)
M. Tiecco et al.
Synthesis, 478-478 (1982)
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