673951

Tricyclopentylphosphine tetrafluoroborate

95%

• Synonym(s): Cyp₃HBF₄, PCyp₃HBF₄
• Empirical Formula (Hill Notation): C₁₅H₂₈BF₄P
• CAS Number: 610756-04-2
• Molecular Weight: 326.16
• MDL number: MFCD08705305
• UNSPSC Code: 12352101
• PubChem Substance ID: 24885190

Properties

• assay: 95%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Cross Couplings
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 246-264 °C
• functional group: phosphine
• greener alternative category: , Aligned
• SMILES string: F[B-](F)(F)F.C1CCC(C1)[PH+](C2CCCC2)C3CCCC3
• InChI: 1S/C15H27P.BF4/c1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;2-1(3,4)5/h13-15H,1-12H2;/q;-1/p+1
• InChI key: KTDMVANQORSVPI-UHFFFAOYSA-O

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Catalyst for alkane C-H arylation from aryl chlorides

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.

Safety Information

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges