526304
Cyanoborohydride, polymer supported
macroporous, 20-50 mesh, extent of labeling: ~2.0-3.5 mmol/g loading
Synonym(s):
Cyanoborohydride on Amberlite™ IRA-400
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5 G
$85.28
25 G
$390.00
About This Item
$85.28
List Price$107.00Save 20%Web-Only Promotion
Available to ship onApril 29, 2025Details
Request a Bulk Order
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form
macroporous
Quality Level
reaction suitability
reaction type: solution phase peptide synthesis
reactivity: imine reactive
extent of labeling
~2.0-3.5 mmol/g loading
particle size
20-50 mesh
mp
>300 °C (lit.)
storage temp.
2-8°C
Related Categories
General description
Cyanoborohydride, polymer supported: is a polymer-supported reducing agent used in reductive amination reactions at room temperature.[1]
application
Polymer supported cyanoborohydride (PSCBH) has been used in the reductive alkylation aminocyclitols for the preparation of corresponding secondary amines.[1]
It can also be used:
It can also be used:
- In combination with manganese dioxide (MnO2) for one-pot conversion of alcohols to secondary or tertiary amines.[2]
- In the synthesis of natural products, (±)-oxomaritidine and (±)-epimaritidine.[3]
Legal Information
Amberlite is a trademark of DuPont de Nemours, Inc.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Ley, S.V.
J. Chem. Soc., Perkin Trans., 2239-2239 (1998)
Synthesis of the alkaloids (?)-oxomaritidine and (?)-epimaritidine using an orchestrated multi-step sequence of polymer supported reagents
Ley S, et al.
Journal of the Chemical Society. Perkin Transactions 1, 3(10), 1251-1252 (1999)
Habermann, J.
J. Chem. Soc., Perkin Trans., 3127-3127 (1998)
In situ oxidation- imine formation- reduction routes from alcohols to amines
Blackburn L and Taylor RJK
Organic Letters, 3(11), 1637-1639 (2001)
Small-Scale One-Pot Reductive Alkylation of Unprotected Aminocyclitols with Supported Reagents
Sisa M, et al.
Synthesis, 2008(19), 3167-3170 (2008)
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