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499552

Sigma-Aldrich

Zinc preparation

5 g/dL Zn+2 in THF, highly reactive Rieke®metal

Synonym(s):

Zn

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100 ML
$760.00

$760.00

Available to ship onMay 01, 2025Details

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100 ML
$760.00

About This Item

Linear Formula:
Zn
CAS Number:
7440-66-6
Molecular Weight:
65.39
MDL number:
MFCD00011291
UNSPSC Code:
12161600
PubChem Substance ID:
24873288
NACRES:
NA.22

$760.00

Available to ship onMay 01, 2025Details

Request a Bulk Order

Quality Level

100

reaction suitability

core: zinc
reagent type: catalyst

concentration

5 g/dL Zn+2 in THF

density

0.949 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

Application

Rieke® Zinc metal can be used to reduce common organic functional groups such as aromatic nitro, conjugated aldehydes, arylacetylenes, and phenylpropiolates.[1]

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

1.0 °F - closed cup

flash_point_c

-17.22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS1564
SHBN6185
SHBM5384
SHBL3135
SHBH6880

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Rieke zinc as a reducing agent for common organic functional groups
Kroemer J, et al.
Tetrahedron Letters, 47(36), 6339-6341 (2006)
Lena Martin et al.
Archives of animal nutrition, 67(3), 248-261 (2013-06-08)
This study aimed at investigating the effect of dietary zinc on performance, jejunal brush border membrane enzyme activities and mRNA levels of enzymes and two zinc transporters in piglets. A total of 126 piglets were weaned at 26 ±1 days
W Reainthippayasakul et al.
Journal of nanoscience and nanotechnology, 13(5), 3617-3621 (2013-07-19)
Conjugated meso-alkynyl 5,15-dimesitylporphyrin metal complexes have been synthesized by Sonogashira coupling reaction in good yields. Alkynyl groups were chosen as a link at the meso positions in order to extend the pi-conjugated length of porphyrin rings. These synthesized porphyrin derivatives
Bikha Ram Devrajani et al.
JPMA. The Journal of the Pakistan Medical Association, 63(3), 369-373 (2013-08-07)
To determine the serum zinc level in patients with pneumonia. The descriptive cross-sectional study was conducted at the Liaquat University Hospital, Hyderabad, Pakistan, from September 2008 to February 2009. All patients above 12 years of age and of either gender
I A Popov et al.
Molekuliarnaia biologiia, 47(3), 498-504 (2013-07-31)
Alzheimer's disease, is a lethal neurodegenerative pathology, characterized by the formation of soluble neurotoxic oligomers of the human amyloid-beta peptide Abeta which get accumulated forming polymeric extracellular aggregates (so-called amyloid plaques). The isomerized at aspartate 7 isoform of the human
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Articles

Rieke® Highly Reactive Metals

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

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