Contains THF, should be advertised as Mg(nBu)2(THF)2 for clarity.
345113
Di-n-butylmagnesium solution
Di-n-butylmagnesium solution
1.0 M in heptane
Synonym(s):
Bis-n-butylmagnesium, Dibutylmagnesium
Sign Into View Organizational & Contract Pricing
Select a Size
100 ML
$129.00
800 ML
$1,010.00
All Photos(1)
Select a Size
Change View
100 ML
$129.00
800 ML
$1,010.00
About This Item
Linear Formula:
[CH3(CH2)3]2Mg
CAS Number:
Molecular Weight:
138.53
Beilstein/REAXYS Number:
3535184
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in heptane
density
0.713 g/mL at 25 °C
SMILES string
CCCC[Mg]CCCC
InChI
1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
InChI key
ODHFJIDDBSDWNU-UHFFFAOYSA-N
Looking for similar products? Visit Product Comparison Guide
Related Categories
General description
Di-n-butylmagnesium solution is a useful reagent for the synthesis of organomagnesium compounds.
Application
Di-n-butylmagnesium solution can be used as a reagent for the deprotection of aromatic and aliphatic benzyl thioethers to synthesize corresponding benzylthiols in the presence of titanocene dichloride[1]. It can also be used as a catalyst to synthesize enantioenriched nitrogen-containing heterocyclic derivatives by the asymmetric ring-opening reaction of aziridines with substituted tetrazoles in the presence of chiral ligand[2].
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk_germany
WGK 2
flash_point_f
21.2 °F - closed cup
flash_point_c
-6 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Customers Also Viewed
Dan Li et al.
Organic letters, 19(12), 3211-3214 (2017-05-31)
A magnesium-catalyzed asymmetric ring-opening reaction of aziridines with substituted tetrazoles is reported. The current protocol proceeds smoothly and gives the corresponding desymmetrization products in high yields and good enantioselectivities. A new chiral ligand was synthesized from azetidine and (R)-BINOL and
A mild and practical deprotection method for benzyl thioethers
Akao A, et al.
Tetrahedron Letters, 47, 5337-5340 (2006)
Active Filters
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service
